Bis[1-phenyl-3-(1H-1,2,4-triazol-1-yl-κN (4))propan-1-one]bis­(thio­cyanato-κN)copper(II)

The title compound, [Cu(NCS)(2)(C(11)H(11)N(3)O)(2)], contains two independent Cu(II) atoms. Each Cu(II) atom, lying on an inversion center, is coordinated by two N atoms from two NCS(−) anions and two N atoms from two monodentate 1-phenyl-3-(1H-1,2,4-triazol-1-yl)propan-1-one ligands in a distorted...

Descripción completa

Detalles Bibliográficos
Autores principales: Cai, Hua, Guo, Ying, Li, Jian-Gang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414160/
https://www.ncbi.nlm.nih.gov/pubmed/22904767
http://dx.doi.org/10.1107/S160053681203108X
Descripción
Sumario:The title compound, [Cu(NCS)(2)(C(11)H(11)N(3)O)(2)], contains two independent Cu(II) atoms. Each Cu(II) atom, lying on an inversion center, is coordinated by two N atoms from two NCS(−) anions and two N atoms from two monodentate 1-phenyl-3-(1H-1,2,4-triazol-1-yl)propan-1-one ligands in a distorted square-planar geometry. Two S atoms from adjacent mol­ecules occupy the axial positions with long Cu⋯S distances [3.0495 (10) and 3.1045 (9) Å] and complete the overall distorted octahedral coordination sphere. Weak inter­molecular C—H⋯O hydrogen bonds are present.

Ejemplares similares