Bis[1-phenyl-3-(1H-1,2,4-triazol-1-yl-κN (4))propan-1-one]bis­(thio­cyanato-κN)copper(II)

The title compound, [Cu(NCS)(2)(C(11)H(11)N(3)O)(2)], contains two independent Cu(II) atoms. Each Cu(II) atom, lying on an inversion center, is coordinated by two N atoms from two NCS(−) anions and two N atoms from two monodentate 1-phenyl-3-(1H-1,2,4-triazol-1-yl)propan-1-one ligands in a distorted...

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Detalles Bibliográficos
Autores principales: Cai, Hua, Guo, Ying, Li, Jian-Gang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414160/
https://www.ncbi.nlm.nih.gov/pubmed/22904767
http://dx.doi.org/10.1107/S160053681203108X
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author Cai, Hua
Guo, Ying
Li, Jian-Gang
author_facet Cai, Hua
Guo, Ying
Li, Jian-Gang
author_sort Cai, Hua
collection PubMed
description The title compound, [Cu(NCS)(2)(C(11)H(11)N(3)O)(2)], contains two independent Cu(II) atoms. Each Cu(II) atom, lying on an inversion center, is coordinated by two N atoms from two NCS(−) anions and two N atoms from two monodentate 1-phenyl-3-(1H-1,2,4-triazol-1-yl)propan-1-one ligands in a distorted square-planar geometry. Two S atoms from adjacent mol­ecules occupy the axial positions with long Cu⋯S distances [3.0495 (10) and 3.1045 (9) Å] and complete the overall distorted octahedral coordination sphere. Weak inter­molecular C—H⋯O hydrogen bonds are present.
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spelling pubmed-34141602012-08-17 Bis[1-phenyl-3-(1H-1,2,4-triazol-1-yl-κN (4))propan-1-one]bis­(thio­cyanato-κN)copper(II) Cai, Hua Guo, Ying Li, Jian-Gang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(NCS)(2)(C(11)H(11)N(3)O)(2)], contains two independent Cu(II) atoms. Each Cu(II) atom, lying on an inversion center, is coordinated by two N atoms from two NCS(−) anions and two N atoms from two monodentate 1-phenyl-3-(1H-1,2,4-triazol-1-yl)propan-1-one ligands in a distorted square-planar geometry. Two S atoms from adjacent mol­ecules occupy the axial positions with long Cu⋯S distances [3.0495 (10) and 3.1045 (9) Å] and complete the overall distorted octahedral coordination sphere. Weak inter­molecular C—H⋯O hydrogen bonds are present. International Union of Crystallography 2012-07-25 /pmc/articles/PMC3414160/ /pubmed/22904767 http://dx.doi.org/10.1107/S160053681203108X Text en © Cai et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Cai, Hua
Guo, Ying
Li, Jian-Gang
Bis[1-phenyl-3-(1H-1,2,4-triazol-1-yl-κN (4))propan-1-one]bis­(thio­cyanato-κN)copper(II)
title Bis[1-phenyl-3-(1H-1,2,4-triazol-1-yl-κN (4))propan-1-one]bis­(thio­cyanato-κN)copper(II)
title_full Bis[1-phenyl-3-(1H-1,2,4-triazol-1-yl-κN (4))propan-1-one]bis­(thio­cyanato-κN)copper(II)
title_fullStr Bis[1-phenyl-3-(1H-1,2,4-triazol-1-yl-κN (4))propan-1-one]bis­(thio­cyanato-κN)copper(II)
title_full_unstemmed Bis[1-phenyl-3-(1H-1,2,4-triazol-1-yl-κN (4))propan-1-one]bis­(thio­cyanato-κN)copper(II)
title_short Bis[1-phenyl-3-(1H-1,2,4-triazol-1-yl-κN (4))propan-1-one]bis­(thio­cyanato-κN)copper(II)
title_sort bis[1-phenyl-3-(1h-1,2,4-triazol-1-yl-κn (4))propan-1-one]bis­(thio­cyanato-κn)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414160/
https://www.ncbi.nlm.nih.gov/pubmed/22904767
http://dx.doi.org/10.1107/S160053681203108X
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