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Bis(μ-2-carboxymethyl-2-hydroxybutanedioato)bis[diaquamanganese(II)]–1,2-bis(pyridin-4-yl)ethane–water (1/1/2)
The asymmetric unit of the title compound, [Mn(2)(C(6)H(6)O(7))(2)(H(2)O)(4)]·C(12)H(12)N(2)·2H(2)O, comprises half of a centrosymmetric dimer, half of a 1,2-bis(pyridin-4-yl)ethane and one water molecule. Two citrate ligands bridge two Mn(II) ions, the Mn(II) ion being coordinated by four O atoms...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414161/ https://www.ncbi.nlm.nih.gov/pubmed/22904768 http://dx.doi.org/10.1107/S1600536812032771 |
Sumario: | The asymmetric unit of the title compound, [Mn(2)(C(6)H(6)O(7))(2)(H(2)O)(4)]·C(12)H(12)N(2)·2H(2)O, comprises half of a centrosymmetric dimer, half of a 1,2-bis(pyridin-4-yl)ethane and one water molecule. Two citrate ligands bridge two Mn(II) ions, the Mn(II) ion being coordinated by four O atoms from the citrate(2−) ligands and two water O atoms, forming a distorted octahedral environment. In the crystal, O—H⋯O hydrogen bonds link the centrosymmetric dimers and lattice water molecules into a three-dimensional structure which is further stabilized by intermolecular π–π interactions [centroid–centroid distance = 3.792 (2) Å]. |
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