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Bis(μ-2-carboxymethyl-2-hydroxybutanedioato)bis[diaquamanganese(II)]–1,2-bis(pyridin-4-yl)ethane–water (1/1/2)
The asymmetric unit of the title compound, [Mn(2)(C(6)H(6)O(7))(2)(H(2)O)(4)]·C(12)H(12)N(2)·2H(2)O, comprises half of a centrosymmetric dimer, half of a 1,2-bis(pyridin-4-yl)ethane and one water molecule. Two citrate ligands bridge two Mn(II) ions, the Mn(II) ion being coordinated by four O atoms...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414161/ https://www.ncbi.nlm.nih.gov/pubmed/22904768 http://dx.doi.org/10.1107/S1600536812032771 |
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author | Hwang, In Hong Kim, Pan-Gi Kim, Cheal Kim, Youngmee |
author_facet | Hwang, In Hong Kim, Pan-Gi Kim, Cheal Kim, Youngmee |
author_sort | Hwang, In Hong |
collection | PubMed |
description | The asymmetric unit of the title compound, [Mn(2)(C(6)H(6)O(7))(2)(H(2)O)(4)]·C(12)H(12)N(2)·2H(2)O, comprises half of a centrosymmetric dimer, half of a 1,2-bis(pyridin-4-yl)ethane and one water molecule. Two citrate ligands bridge two Mn(II) ions, the Mn(II) ion being coordinated by four O atoms from the citrate(2−) ligands and two water O atoms, forming a distorted octahedral environment. In the crystal, O—H⋯O hydrogen bonds link the centrosymmetric dimers and lattice water molecules into a three-dimensional structure which is further stabilized by intermolecular π–π interactions [centroid–centroid distance = 3.792 (2) Å]. |
format | Online Article Text |
id | pubmed-3414161 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-34141612012-08-17 Bis(μ-2-carboxymethyl-2-hydroxybutanedioato)bis[diaquamanganese(II)]–1,2-bis(pyridin-4-yl)ethane–water (1/1/2) Hwang, In Hong Kim, Pan-Gi Kim, Cheal Kim, Youngmee Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Mn(2)(C(6)H(6)O(7))(2)(H(2)O)(4)]·C(12)H(12)N(2)·2H(2)O, comprises half of a centrosymmetric dimer, half of a 1,2-bis(pyridin-4-yl)ethane and one water molecule. Two citrate ligands bridge two Mn(II) ions, the Mn(II) ion being coordinated by four O atoms from the citrate(2−) ligands and two water O atoms, forming a distorted octahedral environment. In the crystal, O—H⋯O hydrogen bonds link the centrosymmetric dimers and lattice water molecules into a three-dimensional structure which is further stabilized by intermolecular π–π interactions [centroid–centroid distance = 3.792 (2) Å]. International Union of Crystallography 2012-07-25 /pmc/articles/PMC3414161/ /pubmed/22904768 http://dx.doi.org/10.1107/S1600536812032771 Text en © Hwang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Hwang, In Hong Kim, Pan-Gi Kim, Cheal Kim, Youngmee Bis(μ-2-carboxymethyl-2-hydroxybutanedioato)bis[diaquamanganese(II)]–1,2-bis(pyridin-4-yl)ethane–water (1/1/2) |
title | Bis(μ-2-carboxymethyl-2-hydroxybutanedioato)bis[diaquamanganese(II)]–1,2-bis(pyridin-4-yl)ethane–water (1/1/2) |
title_full | Bis(μ-2-carboxymethyl-2-hydroxybutanedioato)bis[diaquamanganese(II)]–1,2-bis(pyridin-4-yl)ethane–water (1/1/2) |
title_fullStr | Bis(μ-2-carboxymethyl-2-hydroxybutanedioato)bis[diaquamanganese(II)]–1,2-bis(pyridin-4-yl)ethane–water (1/1/2) |
title_full_unstemmed | Bis(μ-2-carboxymethyl-2-hydroxybutanedioato)bis[diaquamanganese(II)]–1,2-bis(pyridin-4-yl)ethane–water (1/1/2) |
title_short | Bis(μ-2-carboxymethyl-2-hydroxybutanedioato)bis[diaquamanganese(II)]–1,2-bis(pyridin-4-yl)ethane–water (1/1/2) |
title_sort | bis(μ-2-carboxymethyl-2-hydroxybutanedioato)bis[diaquamanganese(ii)]–1,2-bis(pyridin-4-yl)ethane–water (1/1/2) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414161/ https://www.ncbi.nlm.nih.gov/pubmed/22904768 http://dx.doi.org/10.1107/S1600536812032771 |
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