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Bis(μ-2-carboxymethyl-2-hydroxy­butane­dioato)bis­[diaqua­manganese(II)]–1,2-bis­(pyridin-4-yl)ethane–water (1/1/2)

The asymmetric unit of the title compound, [Mn(2)(C(6)H(6)O(7))(2)(H(2)O)(4)]·C(12)H(12)N(2)·2H(2)O, comprises half of a centrosymmetric dimer, half of a 1,2-bis­(pyridin-4-yl)ethane and one water mol­ecule. Two citrate ligands bridge two Mn(II) ions, the Mn(II) ion being coordinated by four O atoms...

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Detalles Bibliográficos
Autores principales: Hwang, In Hong, Kim, Pan-Gi, Kim, Cheal, Kim, Youngmee
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414161/
https://www.ncbi.nlm.nih.gov/pubmed/22904768
http://dx.doi.org/10.1107/S1600536812032771
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author Hwang, In Hong
Kim, Pan-Gi
Kim, Cheal
Kim, Youngmee
author_facet Hwang, In Hong
Kim, Pan-Gi
Kim, Cheal
Kim, Youngmee
author_sort Hwang, In Hong
collection PubMed
description The asymmetric unit of the title compound, [Mn(2)(C(6)H(6)O(7))(2)(H(2)O)(4)]·C(12)H(12)N(2)·2H(2)O, comprises half of a centrosymmetric dimer, half of a 1,2-bis­(pyridin-4-yl)ethane and one water mol­ecule. Two citrate ligands bridge two Mn(II) ions, the Mn(II) ion being coordinated by four O atoms from the citrate(2−) ligands and two water O atoms, forming a distorted octa­hedral environment. In the crystal, O—H⋯O hydrogen bonds link the centrosymmetric dimers and lattice water mol­ecules into a three-dimensional structure which is further stabilized by inter­molecular π–π inter­actions [centroid–centroid distance = 3.792 (2) Å].
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spelling pubmed-34141612012-08-17 Bis(μ-2-carboxymethyl-2-hydroxy­butane­dioato)bis­[diaqua­manganese(II)]–1,2-bis­(pyridin-4-yl)ethane–water (1/1/2) Hwang, In Hong Kim, Pan-Gi Kim, Cheal Kim, Youngmee Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Mn(2)(C(6)H(6)O(7))(2)(H(2)O)(4)]·C(12)H(12)N(2)·2H(2)O, comprises half of a centrosymmetric dimer, half of a 1,2-bis­(pyridin-4-yl)ethane and one water mol­ecule. Two citrate ligands bridge two Mn(II) ions, the Mn(II) ion being coordinated by four O atoms from the citrate(2−) ligands and two water O atoms, forming a distorted octa­hedral environment. In the crystal, O—H⋯O hydrogen bonds link the centrosymmetric dimers and lattice water mol­ecules into a three-dimensional structure which is further stabilized by inter­molecular π–π inter­actions [centroid–centroid distance = 3.792 (2) Å]. International Union of Crystallography 2012-07-25 /pmc/articles/PMC3414161/ /pubmed/22904768 http://dx.doi.org/10.1107/S1600536812032771 Text en © Hwang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hwang, In Hong
Kim, Pan-Gi
Kim, Cheal
Kim, Youngmee
Bis(μ-2-carboxymethyl-2-hydroxy­butane­dioato)bis­[diaqua­manganese(II)]–1,2-bis­(pyridin-4-yl)ethane–water (1/1/2)
title Bis(μ-2-carboxymethyl-2-hydroxy­butane­dioato)bis­[diaqua­manganese(II)]–1,2-bis­(pyridin-4-yl)ethane–water (1/1/2)
title_full Bis(μ-2-carboxymethyl-2-hydroxy­butane­dioato)bis­[diaqua­manganese(II)]–1,2-bis­(pyridin-4-yl)ethane–water (1/1/2)
title_fullStr Bis(μ-2-carboxymethyl-2-hydroxy­butane­dioato)bis­[diaqua­manganese(II)]–1,2-bis­(pyridin-4-yl)ethane–water (1/1/2)
title_full_unstemmed Bis(μ-2-carboxymethyl-2-hydroxy­butane­dioato)bis­[diaqua­manganese(II)]–1,2-bis­(pyridin-4-yl)ethane–water (1/1/2)
title_short Bis(μ-2-carboxymethyl-2-hydroxy­butane­dioato)bis­[diaqua­manganese(II)]–1,2-bis­(pyridin-4-yl)ethane–water (1/1/2)
title_sort bis(μ-2-carboxymethyl-2-hydroxy­butane­dioato)bis­[diaqua­manganese(ii)]–1,2-bis­(pyridin-4-yl)ethane–water (1/1/2)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414161/
https://www.ncbi.nlm.nih.gov/pubmed/22904768
http://dx.doi.org/10.1107/S1600536812032771
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