Bis{6-bromo-4-chloro-2-[(E)-(2-chloro­phenyl)­imino­meth­yl]­phenolato-κ(2) N,O}copper(II)

In the title compound, [Cu(C(13)H(7)BrCl(2)NO)(2)], or CuL (2) {where HL= 2-[(E)-(2-chloro­phenyl­imino)­meth­yl]-6-bromo-4-chloro­phenol}, the Cu(II) atom is located on an inversion center and has a square-planar coordination. In the crystal, complex mol­ecules are linked via Cu⋯Cl inter­actions [2...

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Detalles Bibliográficos
Autor principal: Ping, Zhang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414162/
https://www.ncbi.nlm.nih.gov/pubmed/22904769
http://dx.doi.org/10.1107/S1600536812025044
Descripción
Sumario:In the title compound, [Cu(C(13)H(7)BrCl(2)NO)(2)], or CuL (2) {where HL= 2-[(E)-(2-chloro­phenyl­imino)­meth­yl]-6-bromo-4-chloro­phenol}, the Cu(II) atom is located on an inversion center and has a square-planar coordination. In the crystal, complex mol­ecules are linked via Cu⋯Cl inter­actions [2.9933 (11) Å], forming a two-dimensional network parallel to the bc plane. They are also Cl⋯Cl inter­actions [3.3709 (14) Å] present, which consolidate the two-dimensional network structure.

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