Bis{6-bromo-4-chloro-2-[(E)-(2-chloro­phenyl)­imino­meth­yl]­phenolato-κ(2) N,O}copper(II)

In the title compound, [Cu(C(13)H(7)BrCl(2)NO)(2)], or CuL (2) {where HL= 2-[(E)-(2-chloro­phenyl­imino)­meth­yl]-6-bromo-4-chloro­phenol}, the Cu(II) atom is located on an inversion center and has a square-planar coordination. In the crystal, complex mol­ecules are linked via Cu⋯Cl inter­actions [2...

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Detalles Bibliográficos
Autor principal: Ping, Zhang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414162/
https://www.ncbi.nlm.nih.gov/pubmed/22904769
http://dx.doi.org/10.1107/S1600536812025044
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author Ping, Zhang
author_facet Ping, Zhang
author_sort Ping, Zhang
collection PubMed
description In the title compound, [Cu(C(13)H(7)BrCl(2)NO)(2)], or CuL (2) {where HL= 2-[(E)-(2-chloro­phenyl­imino)­meth­yl]-6-bromo-4-chloro­phenol}, the Cu(II) atom is located on an inversion center and has a square-planar coordination. In the crystal, complex mol­ecules are linked via Cu⋯Cl inter­actions [2.9933 (11) Å], forming a two-dimensional network parallel to the bc plane. They are also Cl⋯Cl inter­actions [3.3709 (14) Å] present, which consolidate the two-dimensional network structure.
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spelling pubmed-34141622012-08-17 Bis{6-bromo-4-chloro-2-[(E)-(2-chloro­phenyl)­imino­meth­yl]­phenolato-κ(2) N,O}copper(II) Ping, Zhang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(13)H(7)BrCl(2)NO)(2)], or CuL (2) {where HL= 2-[(E)-(2-chloro­phenyl­imino)­meth­yl]-6-bromo-4-chloro­phenol}, the Cu(II) atom is located on an inversion center and has a square-planar coordination. In the crystal, complex mol­ecules are linked via Cu⋯Cl inter­actions [2.9933 (11) Å], forming a two-dimensional network parallel to the bc plane. They are also Cl⋯Cl inter­actions [3.3709 (14) Å] present, which consolidate the two-dimensional network structure. International Union of Crystallography 2012-07-25 /pmc/articles/PMC3414162/ /pubmed/22904769 http://dx.doi.org/10.1107/S1600536812025044 Text en © Zhang Ping 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ping, Zhang
Bis{6-bromo-4-chloro-2-[(E)-(2-chloro­phenyl)­imino­meth­yl]­phenolato-κ(2) N,O}copper(II)
title Bis{6-bromo-4-chloro-2-[(E)-(2-chloro­phenyl)­imino­meth­yl]­phenolato-κ(2) N,O}copper(II)
title_full Bis{6-bromo-4-chloro-2-[(E)-(2-chloro­phenyl)­imino­meth­yl]­phenolato-κ(2) N,O}copper(II)
title_fullStr Bis{6-bromo-4-chloro-2-[(E)-(2-chloro­phenyl)­imino­meth­yl]­phenolato-κ(2) N,O}copper(II)
title_full_unstemmed Bis{6-bromo-4-chloro-2-[(E)-(2-chloro­phenyl)­imino­meth­yl]­phenolato-κ(2) N,O}copper(II)
title_short Bis{6-bromo-4-chloro-2-[(E)-(2-chloro­phenyl)­imino­meth­yl]­phenolato-κ(2) N,O}copper(II)
title_sort bis{6-bromo-4-chloro-2-[(e)-(2-chloro­phenyl)­imino­meth­yl]­phenolato-κ(2) n,o}copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414162/
https://www.ncbi.nlm.nih.gov/pubmed/22904769
http://dx.doi.org/10.1107/S1600536812025044
work_keys_str_mv AT pingzhang bis6bromo4chloro2e2chlorophenyliminomethylphenolatok2nocopperii

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