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[μ-Bis(diphenylarsino)methane-1:2κ(2) As:As]decacarbonyl-1κ(3) C,2κ(3) C,3κ(4) C-triangulo-triosmium(0)
The title compound, [Os(3)(C(25)H(22)As(2))(CO)(10)], contains a triangle of singly bonded Os atoms; both arsine ligands are equatorial with respect to the Os(3) triangle. Each arsine-substituted Os atom bears one equatorial and two axial terminal carbonyl ligands, whereas the unsubstituted Os atom...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414163/ https://www.ncbi.nlm.nih.gov/pubmed/22904770 http://dx.doi.org/10.1107/S1600536812024208 |
| _version_ | 1782240165234737152 |
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| author | Shawkataly, Omar bin Khan, Imthyaz Ahmed Sirat, Siti Syaida Quah, Ching Kheng Fun, Hoong-Kun |
| author_facet | Shawkataly, Omar bin Khan, Imthyaz Ahmed Sirat, Siti Syaida Quah, Ching Kheng Fun, Hoong-Kun |
| author_sort | Shawkataly, Omar bin |
| collection | PubMed |
| description | The title compound, [Os(3)(C(25)H(22)As(2))(CO)(10)], contains a triangle of singly bonded Os atoms; both arsine ligands are equatorial with respect to the Os(3) triangle. Each arsine-substituted Os atom bears one equatorial and two axial terminal carbonyl ligands, whereas the unsubstituted Os atom bears two equatorial and two axial terminal carbonyl ligands. The dihedral angles between the two benzene rings in the diphenylarsino groups are 67.42 (16) and 61.99 (16)°. In the crystal, molecules are linked via C—H⋯O hydrogen bonds into zigzag chains propagating along [010]. |
| format | Online Article Text |
| id | pubmed-3414163 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-34141632012-08-17 [μ-Bis(diphenylarsino)methane-1:2κ(2) As:As]decacarbonyl-1κ(3) C,2κ(3) C,3κ(4) C-triangulo-triosmium(0) Shawkataly, Omar bin Khan, Imthyaz Ahmed Sirat, Siti Syaida Quah, Ching Kheng Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Os(3)(C(25)H(22)As(2))(CO)(10)], contains a triangle of singly bonded Os atoms; both arsine ligands are equatorial with respect to the Os(3) triangle. Each arsine-substituted Os atom bears one equatorial and two axial terminal carbonyl ligands, whereas the unsubstituted Os atom bears two equatorial and two axial terminal carbonyl ligands. The dihedral angles between the two benzene rings in the diphenylarsino groups are 67.42 (16) and 61.99 (16)°. In the crystal, molecules are linked via C—H⋯O hydrogen bonds into zigzag chains propagating along [010]. International Union of Crystallography 2012-07-25 /pmc/articles/PMC3414163/ /pubmed/22904770 http://dx.doi.org/10.1107/S1600536812024208 Text en © Shawkataly et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Shawkataly, Omar bin Khan, Imthyaz Ahmed Sirat, Siti Syaida Quah, Ching Kheng Fun, Hoong-Kun [μ-Bis(diphenylarsino)methane-1:2κ(2) As:As]decacarbonyl-1κ(3) C,2κ(3) C,3κ(4) C-triangulo-triosmium(0) |
| title | [μ-Bis(diphenylarsino)methane-1:2κ(2)
As:As]decacarbonyl-1κ(3)
C,2κ(3)
C,3κ(4)
C-triangulo-triosmium(0) |
| title_full | [μ-Bis(diphenylarsino)methane-1:2κ(2)
As:As]decacarbonyl-1κ(3)
C,2κ(3)
C,3κ(4)
C-triangulo-triosmium(0) |
| title_fullStr | [μ-Bis(diphenylarsino)methane-1:2κ(2)
As:As]decacarbonyl-1κ(3)
C,2κ(3)
C,3κ(4)
C-triangulo-triosmium(0) |
| title_full_unstemmed | [μ-Bis(diphenylarsino)methane-1:2κ(2)
As:As]decacarbonyl-1κ(3)
C,2κ(3)
C,3κ(4)
C-triangulo-triosmium(0) |
| title_short | [μ-Bis(diphenylarsino)methane-1:2κ(2)
As:As]decacarbonyl-1κ(3)
C,2κ(3)
C,3κ(4)
C-triangulo-triosmium(0) |
| title_sort | [μ-bis(diphenylarsino)methane-1:2κ(2)
as:as]decacarbonyl-1κ(3)
c,2κ(3)
c,3κ(4)
c-triangulo-triosmium(0) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414163/ https://www.ncbi.nlm.nih.gov/pubmed/22904770 http://dx.doi.org/10.1107/S1600536812024208 |
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