rac-cis,cis-Dicarbonyl­dichlorido{1-[2-(diphenyl­phosphan­yl)benz­yl]-3-mesityl­imidazol-2-yl­idene}ruthenium(II) dichloro­methane monosolvate

The Ru(II) atom in the title compound, [RuCl(2)(C(31)H(29)N(2)P)(CO)(2)]·CH(2)Cl(2), exhibits a distorted octahedral coordination environment. The bond angles of the cis substituents at the Ru(II) atom range from 82.72 (9) to 97.20 (3)°. This mol­ecule is of inter­est in the field of catalytic trans...

Descripción completa

Detalles Bibliográficos
Autores principales: Domski, Gregory J., Hohenboken, Sallie A., Swenson, Dale C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414164/
https://www.ncbi.nlm.nih.gov/pubmed/22904771
http://dx.doi.org/10.1107/S1600536812032515
_version_ 1782240165453889536
author Domski, Gregory J.
Hohenboken, Sallie A.
Swenson, Dale C.
author_facet Domski, Gregory J.
Hohenboken, Sallie A.
Swenson, Dale C.
author_sort Domski, Gregory J.
collection PubMed
description The Ru(II) atom in the title compound, [RuCl(2)(C(31)H(29)N(2)P)(CO)(2)]·CH(2)Cl(2), exhibits a distorted octahedral coordination environment. The bond angles of the cis substituents at the Ru(II) atom range from 82.72 (9) to 97.20 (3)°. This mol­ecule is of inter­est in the field of catalytic transfer hydrogenation.
format Online
Article
Text
id pubmed-3414164
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-34141642012-08-17 rac-cis,cis-Dicarbonyl­dichlorido{1-[2-(diphenyl­phosphan­yl)benz­yl]-3-mesityl­imidazol-2-yl­idene}ruthenium(II) dichloro­methane monosolvate Domski, Gregory J. Hohenboken, Sallie A. Swenson, Dale C. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Ru(II) atom in the title compound, [RuCl(2)(C(31)H(29)N(2)P)(CO)(2)]·CH(2)Cl(2), exhibits a distorted octahedral coordination environment. The bond angles of the cis substituents at the Ru(II) atom range from 82.72 (9) to 97.20 (3)°. This mol­ecule is of inter­est in the field of catalytic transfer hydrogenation. International Union of Crystallography 2012-07-25 /pmc/articles/PMC3414164/ /pubmed/22904771 http://dx.doi.org/10.1107/S1600536812032515 Text en © Domski et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Domski, Gregory J.
Hohenboken, Sallie A.
Swenson, Dale C.
rac-cis,cis-Dicarbonyl­dichlorido{1-[2-(diphenyl­phosphan­yl)benz­yl]-3-mesityl­imidazol-2-yl­idene}ruthenium(II) dichloro­methane monosolvate
title rac-cis,cis-Dicarbonyl­dichlorido{1-[2-(diphenyl­phosphan­yl)benz­yl]-3-mesityl­imidazol-2-yl­idene}ruthenium(II) dichloro­methane monosolvate
title_full rac-cis,cis-Dicarbonyl­dichlorido{1-[2-(diphenyl­phosphan­yl)benz­yl]-3-mesityl­imidazol-2-yl­idene}ruthenium(II) dichloro­methane monosolvate
title_fullStr rac-cis,cis-Dicarbonyl­dichlorido{1-[2-(diphenyl­phosphan­yl)benz­yl]-3-mesityl­imidazol-2-yl­idene}ruthenium(II) dichloro­methane monosolvate
title_full_unstemmed rac-cis,cis-Dicarbonyl­dichlorido{1-[2-(diphenyl­phosphan­yl)benz­yl]-3-mesityl­imidazol-2-yl­idene}ruthenium(II) dichloro­methane monosolvate
title_short rac-cis,cis-Dicarbonyl­dichlorido{1-[2-(diphenyl­phosphan­yl)benz­yl]-3-mesityl­imidazol-2-yl­idene}ruthenium(II) dichloro­methane monosolvate
title_sort rac-cis,cis-dicarbonyl­dichlorido{1-[2-(diphenyl­phosphan­yl)benz­yl]-3-mesityl­imidazol-2-yl­idene}ruthenium(ii) dichloro­methane monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414164/
https://www.ncbi.nlm.nih.gov/pubmed/22904771
http://dx.doi.org/10.1107/S1600536812032515
work_keys_str_mv AT domskigregoryj racciscisdicarbonyldichlorido12diphenylphosphanylbenzyl3mesitylimidazol2ylidenerutheniumiidichloromethanemonosolvate
AT hohenbokensalliea racciscisdicarbonyldichlorido12diphenylphosphanylbenzyl3mesitylimidazol2ylidenerutheniumiidichloromethanemonosolvate
AT swensondalec racciscisdicarbonyldichlorido12diphenylphosphanylbenzyl3mesitylimidazol2ylidenerutheniumiidichloromethanemonosolvate

Ejemplares similares