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Diaquadi-μ-formato-bis­{μ-2,2′-[propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}cadmium(II)dinickel(II) dihydrate

In the centrosymmetric title compound, [CdNi(2)(C(17)H(16)N(2)O(2))(2)(HCOO)(2)(H(2)O)(2)]·2H(2)O, The Ni(II) cation is chelated by a 2,2′-[propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphen­olate (salpn) anion, and further coordinated by a formate anion and a water mol­ecule in a distorted NiN(2)...

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Detalles Bibliográficos
Autores principales: Zhang, Jian-Feng, Wan, Bo, Liu, Wen, Shi, Qian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414165/
https://www.ncbi.nlm.nih.gov/pubmed/22904772
http://dx.doi.org/10.1107/S1600536812029583
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author Zhang, Jian-Feng
Wan, Bo
Liu, Wen
Shi, Qian
author_facet Zhang, Jian-Feng
Wan, Bo
Liu, Wen
Shi, Qian
author_sort Zhang, Jian-Feng
collection PubMed
description In the centrosymmetric title compound, [CdNi(2)(C(17)H(16)N(2)O(2))(2)(HCOO)(2)(H(2)O)(2)]·2H(2)O, The Ni(II) cation is chelated by a 2,2′-[propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphen­olate (salpn) anion, and further coordinated by a formate anion and a water mol­ecule in a distorted NiN(2)O(4) octa­hedral geometry. The Cd(II) cation, located on an inversion center, is coordinated by four deprotonated hy­droxy groups from two salpn anions and two carboxyl­ate O atoms from formate anions in a distorted octa­hedral geometry. Both formate and salpn anions bridge the Cd and Ni cations, forming a trinuclear complex. Within the salpn anion, the benzene rings are twisted to each other at a dihedral angle of 61.46 (18)°. Inter­molecular O—H⋯O hydrogen bonding is present in the crystal structure. The lattice water mol­ecule is disorder over two positions with an occupancy ratio of 0.75:0.25.
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spelling pubmed-34141652012-08-17 Diaquadi-μ-formato-bis­{μ-2,2′-[propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}cadmium(II)dinickel(II) dihydrate Zhang, Jian-Feng Wan, Bo Liu, Wen Shi, Qian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric title compound, [CdNi(2)(C(17)H(16)N(2)O(2))(2)(HCOO)(2)(H(2)O)(2)]·2H(2)O, The Ni(II) cation is chelated by a 2,2′-[propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphen­olate (salpn) anion, and further coordinated by a formate anion and a water mol­ecule in a distorted NiN(2)O(4) octa­hedral geometry. The Cd(II) cation, located on an inversion center, is coordinated by four deprotonated hy­droxy groups from two salpn anions and two carboxyl­ate O atoms from formate anions in a distorted octa­hedral geometry. Both formate and salpn anions bridge the Cd and Ni cations, forming a trinuclear complex. Within the salpn anion, the benzene rings are twisted to each other at a dihedral angle of 61.46 (18)°. Inter­molecular O—H⋯O hydrogen bonding is present in the crystal structure. The lattice water mol­ecule is disorder over two positions with an occupancy ratio of 0.75:0.25. International Union of Crystallography 2012-07-28 /pmc/articles/PMC3414165/ /pubmed/22904772 http://dx.doi.org/10.1107/S1600536812029583 Text en © Zhang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Jian-Feng
Wan, Bo
Liu, Wen
Shi, Qian
Diaquadi-μ-formato-bis­{μ-2,2′-[propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}cadmium(II)dinickel(II) dihydrate
title Diaquadi-μ-formato-bis­{μ-2,2′-[propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}cadmium(II)dinickel(II) dihydrate
title_full Diaquadi-μ-formato-bis­{μ-2,2′-[propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}cadmium(II)dinickel(II) dihydrate
title_fullStr Diaquadi-μ-formato-bis­{μ-2,2′-[propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}cadmium(II)dinickel(II) dihydrate
title_full_unstemmed Diaquadi-μ-formato-bis­{μ-2,2′-[propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}cadmium(II)dinickel(II) dihydrate
title_short Diaquadi-μ-formato-bis­{μ-2,2′-[propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}cadmium(II)dinickel(II) dihydrate
title_sort diaquadi-μ-formato-bis­{μ-2,2′-[propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}cadmium(ii)dinickel(ii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414165/
https://www.ncbi.nlm.nih.gov/pubmed/22904772
http://dx.doi.org/10.1107/S1600536812029583
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