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Diaquadi-μ-formato-bis{μ-2,2′-[propane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}cadmium(II)dinickel(II) dihydrate
In the centrosymmetric title compound, [CdNi(2)(C(17)H(16)N(2)O(2))(2)(HCOO)(2)(H(2)O)(2)]·2H(2)O, The Ni(II) cation is chelated by a 2,2′-[propane-1,3-diylbis(nitrilomethanylylidene)]diphenolate (salpn) anion, and further coordinated by a formate anion and a water molecule in a distorted NiN(2)...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414165/ https://www.ncbi.nlm.nih.gov/pubmed/22904772 http://dx.doi.org/10.1107/S1600536812029583 |
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author | Zhang, Jian-Feng Wan, Bo Liu, Wen Shi, Qian |
author_facet | Zhang, Jian-Feng Wan, Bo Liu, Wen Shi, Qian |
author_sort | Zhang, Jian-Feng |
collection | PubMed |
description | In the centrosymmetric title compound, [CdNi(2)(C(17)H(16)N(2)O(2))(2)(HCOO)(2)(H(2)O)(2)]·2H(2)O, The Ni(II) cation is chelated by a 2,2′-[propane-1,3-diylbis(nitrilomethanylylidene)]diphenolate (salpn) anion, and further coordinated by a formate anion and a water molecule in a distorted NiN(2)O(4) octahedral geometry. The Cd(II) cation, located on an inversion center, is coordinated by four deprotonated hydroxy groups from two salpn anions and two carboxylate O atoms from formate anions in a distorted octahedral geometry. Both formate and salpn anions bridge the Cd and Ni cations, forming a trinuclear complex. Within the salpn anion, the benzene rings are twisted to each other at a dihedral angle of 61.46 (18)°. Intermolecular O—H⋯O hydrogen bonding is present in the crystal structure. The lattice water molecule is disorder over two positions with an occupancy ratio of 0.75:0.25. |
format | Online Article Text |
id | pubmed-3414165 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-34141652012-08-17 Diaquadi-μ-formato-bis{μ-2,2′-[propane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}cadmium(II)dinickel(II) dihydrate Zhang, Jian-Feng Wan, Bo Liu, Wen Shi, Qian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric title compound, [CdNi(2)(C(17)H(16)N(2)O(2))(2)(HCOO)(2)(H(2)O)(2)]·2H(2)O, The Ni(II) cation is chelated by a 2,2′-[propane-1,3-diylbis(nitrilomethanylylidene)]diphenolate (salpn) anion, and further coordinated by a formate anion and a water molecule in a distorted NiN(2)O(4) octahedral geometry. The Cd(II) cation, located on an inversion center, is coordinated by four deprotonated hydroxy groups from two salpn anions and two carboxylate O atoms from formate anions in a distorted octahedral geometry. Both formate and salpn anions bridge the Cd and Ni cations, forming a trinuclear complex. Within the salpn anion, the benzene rings are twisted to each other at a dihedral angle of 61.46 (18)°. Intermolecular O—H⋯O hydrogen bonding is present in the crystal structure. The lattice water molecule is disorder over two positions with an occupancy ratio of 0.75:0.25. International Union of Crystallography 2012-07-28 /pmc/articles/PMC3414165/ /pubmed/22904772 http://dx.doi.org/10.1107/S1600536812029583 Text en © Zhang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhang, Jian-Feng Wan, Bo Liu, Wen Shi, Qian Diaquadi-μ-formato-bis{μ-2,2′-[propane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}cadmium(II)dinickel(II) dihydrate |
title | Diaquadi-μ-formato-bis{μ-2,2′-[propane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}cadmium(II)dinickel(II) dihydrate |
title_full | Diaquadi-μ-formato-bis{μ-2,2′-[propane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}cadmium(II)dinickel(II) dihydrate |
title_fullStr | Diaquadi-μ-formato-bis{μ-2,2′-[propane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}cadmium(II)dinickel(II) dihydrate |
title_full_unstemmed | Diaquadi-μ-formato-bis{μ-2,2′-[propane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}cadmium(II)dinickel(II) dihydrate |
title_short | Diaquadi-μ-formato-bis{μ-2,2′-[propane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}cadmium(II)dinickel(II) dihydrate |
title_sort | diaquadi-μ-formato-bis{μ-2,2′-[propane-1,3-diylbis(nitrilomethanylylidene)]diphenolato}cadmium(ii)dinickel(ii) dihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414165/ https://www.ncbi.nlm.nih.gov/pubmed/22904772 http://dx.doi.org/10.1107/S1600536812029583 |
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