Dibromido(dimethyl sulfoxide-κO)(6-methyl-2,2′-bipyridine-κ(2) N,N′)cadmium

In the title compound, [CdBr(2)(C(11)H(10)N(2))(C(2)H(6)OS)], the Cd(II) atom is five-coordinated in a distorted trigonal–bipyramidal geometry by two N atoms from a 6-methyl-2,2′-bipyridine ligand, one O atom from a dimethyl sulfoxide ligand and two Br atoms. An intra­molecular C—H⋯O hydrogen bond o...

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Detalles Bibliográficos
Autores principales: Shirvan, Sadif A., Haydari Dezfuli, Sara
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414166/
https://www.ncbi.nlm.nih.gov/pubmed/22904773
http://dx.doi.org/10.1107/S1600536812033168
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author Shirvan, Sadif A.
Haydari Dezfuli, Sara
author_facet Shirvan, Sadif A.
Haydari Dezfuli, Sara
author_sort Shirvan, Sadif A.
collection PubMed
description In the title compound, [CdBr(2)(C(11)H(10)N(2))(C(2)H(6)OS)], the Cd(II) atom is five-coordinated in a distorted trigonal–bipyramidal geometry by two N atoms from a 6-methyl-2,2′-bipyridine ligand, one O atom from a dimethyl sulfoxide ligand and two Br atoms. An intra­molecular C—H⋯O hydrogen bond occurs. The crystal structure is stabilized by C—H⋯Br hydrogen bonds and π–π contacts between the pyridine rings [centroid–centroid distances = 3.582 (5) and 3.582 (5) Å].
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spelling pubmed-34141662012-08-17 Dibromido(dimethyl sulfoxide-κO)(6-methyl-2,2′-bipyridine-κ(2) N,N′)cadmium Shirvan, Sadif A. Haydari Dezfuli, Sara Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CdBr(2)(C(11)H(10)N(2))(C(2)H(6)OS)], the Cd(II) atom is five-coordinated in a distorted trigonal–bipyramidal geometry by two N atoms from a 6-methyl-2,2′-bipyridine ligand, one O atom from a dimethyl sulfoxide ligand and two Br atoms. An intra­molecular C—H⋯O hydrogen bond occurs. The crystal structure is stabilized by C—H⋯Br hydrogen bonds and π–π contacts between the pyridine rings [centroid–centroid distances = 3.582 (5) and 3.582 (5) Å]. International Union of Crystallography 2012-07-28 /pmc/articles/PMC3414166/ /pubmed/22904773 http://dx.doi.org/10.1107/S1600536812033168 Text en © Shirvan and Haydari Dezfuli 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shirvan, Sadif A.
Haydari Dezfuli, Sara
Dibromido(dimethyl sulfoxide-κO)(6-methyl-2,2′-bipyridine-κ(2) N,N′)cadmium
title Dibromido(dimethyl sulfoxide-κO)(6-methyl-2,2′-bipyridine-κ(2) N,N′)cadmium
title_full Dibromido(dimethyl sulfoxide-κO)(6-methyl-2,2′-bipyridine-κ(2) N,N′)cadmium
title_fullStr Dibromido(dimethyl sulfoxide-κO)(6-methyl-2,2′-bipyridine-κ(2) N,N′)cadmium
title_full_unstemmed Dibromido(dimethyl sulfoxide-κO)(6-methyl-2,2′-bipyridine-κ(2) N,N′)cadmium
title_short Dibromido(dimethyl sulfoxide-κO)(6-methyl-2,2′-bipyridine-κ(2) N,N′)cadmium
title_sort dibromido(dimethyl sulfoxide-κo)(6-methyl-2,2′-bipyridine-κ(2) n,n′)cadmium
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414166/
https://www.ncbi.nlm.nih.gov/pubmed/22904773
http://dx.doi.org/10.1107/S1600536812033168
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