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Diaqua­bis­(4-formyl­benzoato-κO (1))bis­(nicotinamide-κN (1))zinc

In the title complex, [Zn(C(8)H(5)O(3))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Zn(II) cation is located on an inversion center and is coordinated by two 4-formyl­benzoate (FB) anions, two nicotinamide (NA) ligands and two water mol­ecules. The four O atoms in the equatorial plane around the Zn(II) cat...

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Detalles Bibliográficos
Autores principales: Sertçelik, Mustafa, Çaylak Delibaş, Nagihan, Necefoğlu, Hacali, Hökelek, Tuncer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414168/
https://www.ncbi.nlm.nih.gov/pubmed/22904775
http://dx.doi.org/10.1107/S160053681203320X
Descripción
Sumario:In the title complex, [Zn(C(8)H(5)O(3))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Zn(II) cation is located on an inversion center and is coordinated by two 4-formyl­benzoate (FB) anions, two nicotinamide (NA) ligands and two water mol­ecules. The four O atoms in the equatorial plane around the Zn(II) cation form a slightly distorted square-planar arrangement, while the slightly distorted octa­hedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxyl­ate group and the adjacent benzene ring is 24.13 (8)°, while the pyridine ring and the benzene ring are oriented at a dihedral angle of 88.52 (4)°. The coordinating water mol­ecule links with the carboxyl­ate group via an O—H⋯O hydrogen bond. In the crystal, N—H⋯O and O—H⋯O hydrogen bonds, and a weak C—H⋯π inter­action link the mol­ecules into a two-dimensional network parallel to (010). These networks are linked via C—H⋯O and π–π inter­actions between inversion-related benzene rings [centroid–centroid distance = 3.8483 (7) Å], forming a three-dimensional supra­molecular structure.