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cis-Diiodido(N,N,N′,N′-tetramethylethylenediamine-κ(2) N,N′)palladium(II)
In the title complex, cis-[PdI(2)(C(6)H(16)N(2))], the Pd(II) atom lies on a crystallographic twofold rotation axis and is four-coordinated by the two N atoms of a chelating N,N,N′,N′-tetramethylethylenediamine ligand [Pd—N = 2.125 (3) Å] and two I atoms [Pd—I = 2.5833 (4) Å], displaying a distort...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414169/ https://www.ncbi.nlm.nih.gov/pubmed/22904776 http://dx.doi.org/10.1107/S1600536812033004 |
| _version_ | 1782240166613614592 |
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| author | Abellán-López, Antonio Chicote-Olalla, María Teresa Bautista-Cerezo, Delia |
| author_facet | Abellán-López, Antonio Chicote-Olalla, María Teresa Bautista-Cerezo, Delia |
| author_sort | Abellán-López, Antonio |
| collection | PubMed |
| description | In the title complex, cis-[PdI(2)(C(6)H(16)N(2))], the Pd(II) atom lies on a crystallographic twofold rotation axis and is four-coordinated by the two N atoms of a chelating N,N,N′,N′-tetramethylethylenediamine ligand [Pd—N = 2.125 (3) Å] and two I atoms [Pd—I = 2.5833 (4) Å], displaying a distorted square-planar geometry (r.m.s. deviation = 0.005 Å), imposed by the small bite of the chelating ligand [N—Pd—N angle = 84.68 (18)°]. |
| format | Online Article Text |
| id | pubmed-3414169 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-34141692012-08-17 cis-Diiodido(N,N,N′,N′-tetramethylethylenediamine-κ(2) N,N′)palladium(II) Abellán-López, Antonio Chicote-Olalla, María Teresa Bautista-Cerezo, Delia Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, cis-[PdI(2)(C(6)H(16)N(2))], the Pd(II) atom lies on a crystallographic twofold rotation axis and is four-coordinated by the two N atoms of a chelating N,N,N′,N′-tetramethylethylenediamine ligand [Pd—N = 2.125 (3) Å] and two I atoms [Pd—I = 2.5833 (4) Å], displaying a distorted square-planar geometry (r.m.s. deviation = 0.005 Å), imposed by the small bite of the chelating ligand [N—Pd—N angle = 84.68 (18)°]. International Union of Crystallography 2012-07-28 /pmc/articles/PMC3414169/ /pubmed/22904776 http://dx.doi.org/10.1107/S1600536812033004 Text en © Abellán-López et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Abellán-López, Antonio Chicote-Olalla, María Teresa Bautista-Cerezo, Delia cis-Diiodido(N,N,N′,N′-tetramethylethylenediamine-κ(2) N,N′)palladium(II) |
| title |
cis-Diiodido(N,N,N′,N′-tetramethylethylenediamine-κ(2)
N,N′)palladium(II) |
| title_full |
cis-Diiodido(N,N,N′,N′-tetramethylethylenediamine-κ(2)
N,N′)palladium(II) |
| title_fullStr |
cis-Diiodido(N,N,N′,N′-tetramethylethylenediamine-κ(2)
N,N′)palladium(II) |
| title_full_unstemmed |
cis-Diiodido(N,N,N′,N′-tetramethylethylenediamine-κ(2)
N,N′)palladium(II) |
| title_short |
cis-Diiodido(N,N,N′,N′-tetramethylethylenediamine-κ(2)
N,N′)palladium(II) |
| title_sort | cis-diiodido(n,n,n′,n′-tetramethylethylenediamine-κ(2)
n,n′)palladium(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414169/ https://www.ncbi.nlm.nih.gov/pubmed/22904776 http://dx.doi.org/10.1107/S1600536812033004 |
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