Cargando…

Tetra­aqua­bis­[5-(pyridin-4-yl)tetra­zolido N (5)-oxide-κN (2)]manganese(II)

The title compound, [Mn(C(6)H(4)N(5)O)(2)(H(2)O)(4)], is isotypic with its Zn, Ni and Cd analogues reported recently. In the crystal, the Mn(II) cations are coordinated by four O atoms from four aqua ligands and two N atoms from two 5-(pyridin-4-yl)tetra­zolide N(5)-oxide ligands in a distorted octa...

Descripción completa

Detalles Bibliográficos
Autores principales: Jing, Xiang, Luo, Ya
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414170/
https://www.ncbi.nlm.nih.gov/pubmed/22904777
http://dx.doi.org/10.1107/S1600536812032618
_version_ 1782240166832766976
author Jing, Xiang
Luo, Ya
author_facet Jing, Xiang
Luo, Ya
author_sort Jing, Xiang
collection PubMed
description The title compound, [Mn(C(6)H(4)N(5)O)(2)(H(2)O)(4)], is isotypic with its Zn, Ni and Cd analogues reported recently. In the crystal, the Mn(II) cations are coordinated by four O atoms from four aqua ligands and two N atoms from two 5-(pyridin-4-yl)tetra­zolide N(5)-oxide ligands in a distorted octa­hedral coordination environment. The asymmetric unit consists of one Mn(II) cation located on a crystallographic twofold axis, and two crystallographically independent water mol­ecules and one N-donor ligand in general positions. The discrete complex mol­ecules are arranged in alternating rows parallel to [100] and are linked by O—H⋯N and O—H⋯O hydrogen bonds into a three-dimensional network.
format Online
Article
Text
id pubmed-3414170
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-34141702012-08-17 Tetra­aqua­bis­[5-(pyridin-4-yl)tetra­zolido N (5)-oxide-κN (2)]manganese(II) Jing, Xiang Luo, Ya Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Mn(C(6)H(4)N(5)O)(2)(H(2)O)(4)], is isotypic with its Zn, Ni and Cd analogues reported recently. In the crystal, the Mn(II) cations are coordinated by four O atoms from four aqua ligands and two N atoms from two 5-(pyridin-4-yl)tetra­zolide N(5)-oxide ligands in a distorted octa­hedral coordination environment. The asymmetric unit consists of one Mn(II) cation located on a crystallographic twofold axis, and two crystallographically independent water mol­ecules and one N-donor ligand in general positions. The discrete complex mol­ecules are arranged in alternating rows parallel to [100] and are linked by O—H⋯N and O—H⋯O hydrogen bonds into a three-dimensional network. International Union of Crystallography 2012-07-28 /pmc/articles/PMC3414170/ /pubmed/22904777 http://dx.doi.org/10.1107/S1600536812032618 Text en © Jing and Luo 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Jing, Xiang
Luo, Ya
Tetra­aqua­bis­[5-(pyridin-4-yl)tetra­zolido N (5)-oxide-κN (2)]manganese(II)
title Tetra­aqua­bis­[5-(pyridin-4-yl)tetra­zolido N (5)-oxide-κN (2)]manganese(II)
title_full Tetra­aqua­bis­[5-(pyridin-4-yl)tetra­zolido N (5)-oxide-κN (2)]manganese(II)
title_fullStr Tetra­aqua­bis­[5-(pyridin-4-yl)tetra­zolido N (5)-oxide-κN (2)]manganese(II)
title_full_unstemmed Tetra­aqua­bis­[5-(pyridin-4-yl)tetra­zolido N (5)-oxide-κN (2)]manganese(II)
title_short Tetra­aqua­bis­[5-(pyridin-4-yl)tetra­zolido N (5)-oxide-κN (2)]manganese(II)
title_sort tetra­aqua­bis­[5-(pyridin-4-yl)tetra­zolido n (5)-oxide-κn (2)]manganese(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414170/
https://www.ncbi.nlm.nih.gov/pubmed/22904777
http://dx.doi.org/10.1107/S1600536812032618
work_keys_str_mv AT jingxiang tetraaquabis5pyridin4yltetrazolidon5oxidekn2manganeseii
AT luoya tetraaquabis5pyridin4yltetrazolidon5oxidekn2manganeseii