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Tetraaquabis[5-(pyridin-4-yl)tetrazolido N (5)-oxide-κN (2)]manganese(II)
The title compound, [Mn(C(6)H(4)N(5)O)(2)(H(2)O)(4)], is isotypic with its Zn, Ni and Cd analogues reported recently. In the crystal, the Mn(II) cations are coordinated by four O atoms from four aqua ligands and two N atoms from two 5-(pyridin-4-yl)tetrazolide N(5)-oxide ligands in a distorted octa...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414170/ https://www.ncbi.nlm.nih.gov/pubmed/22904777 http://dx.doi.org/10.1107/S1600536812032618 |
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author | Jing, Xiang Luo, Ya |
author_facet | Jing, Xiang Luo, Ya |
author_sort | Jing, Xiang |
collection | PubMed |
description | The title compound, [Mn(C(6)H(4)N(5)O)(2)(H(2)O)(4)], is isotypic with its Zn, Ni and Cd analogues reported recently. In the crystal, the Mn(II) cations are coordinated by four O atoms from four aqua ligands and two N atoms from two 5-(pyridin-4-yl)tetrazolide N(5)-oxide ligands in a distorted octahedral coordination environment. The asymmetric unit consists of one Mn(II) cation located on a crystallographic twofold axis, and two crystallographically independent water molecules and one N-donor ligand in general positions. The discrete complex molecules are arranged in alternating rows parallel to [100] and are linked by O—H⋯N and O—H⋯O hydrogen bonds into a three-dimensional network. |
format | Online Article Text |
id | pubmed-3414170 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-34141702012-08-17 Tetraaquabis[5-(pyridin-4-yl)tetrazolido N (5)-oxide-κN (2)]manganese(II) Jing, Xiang Luo, Ya Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Mn(C(6)H(4)N(5)O)(2)(H(2)O)(4)], is isotypic with its Zn, Ni and Cd analogues reported recently. In the crystal, the Mn(II) cations are coordinated by four O atoms from four aqua ligands and two N atoms from two 5-(pyridin-4-yl)tetrazolide N(5)-oxide ligands in a distorted octahedral coordination environment. The asymmetric unit consists of one Mn(II) cation located on a crystallographic twofold axis, and two crystallographically independent water molecules and one N-donor ligand in general positions. The discrete complex molecules are arranged in alternating rows parallel to [100] and are linked by O—H⋯N and O—H⋯O hydrogen bonds into a three-dimensional network. International Union of Crystallography 2012-07-28 /pmc/articles/PMC3414170/ /pubmed/22904777 http://dx.doi.org/10.1107/S1600536812032618 Text en © Jing and Luo 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Jing, Xiang Luo, Ya Tetraaquabis[5-(pyridin-4-yl)tetrazolido N (5)-oxide-κN (2)]manganese(II) |
title | Tetraaquabis[5-(pyridin-4-yl)tetrazolido N
(5)-oxide-κN
(2)]manganese(II) |
title_full | Tetraaquabis[5-(pyridin-4-yl)tetrazolido N
(5)-oxide-κN
(2)]manganese(II) |
title_fullStr | Tetraaquabis[5-(pyridin-4-yl)tetrazolido N
(5)-oxide-κN
(2)]manganese(II) |
title_full_unstemmed | Tetraaquabis[5-(pyridin-4-yl)tetrazolido N
(5)-oxide-κN
(2)]manganese(II) |
title_short | Tetraaquabis[5-(pyridin-4-yl)tetrazolido N
(5)-oxide-κN
(2)]manganese(II) |
title_sort | tetraaquabis[5-(pyridin-4-yl)tetrazolido n
(5)-oxide-κn
(2)]manganese(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414170/ https://www.ncbi.nlm.nih.gov/pubmed/22904777 http://dx.doi.org/10.1107/S1600536812032618 |
work_keys_str_mv | AT jingxiang tetraaquabis5pyridin4yltetrazolidon5oxidekn2manganeseii AT luoya tetraaquabis5pyridin4yltetrazolidon5oxidekn2manganeseii |