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catena-Poly[[(2-{[2-(dimethylammonio)ethyl]iminomethyl}pyridine-κ(2) N,N′)bis(thiocyanato-κN)manganese(II)]-μ-thiocyanato-κ(2) N:S]
In the title one-dimensional coordination polymer, [Mn(NCS)(3)(C(10)H(16)N(3))](n), the Mn(II) atom is coordinated by an N,N′-bidentate Schiff base and four thiocyanate ligands in a distorted octahedral N(5)S geometry. Bridging thiocyanate ligands interconnect adjacent [Mn(NCS)(2)(C(10)H(16)N(3)...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414171/ https://www.ncbi.nlm.nih.gov/pubmed/22904778 http://dx.doi.org/10.1107/S1600536812032874 |
| _version_ | 1782240167070793728 |
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| author | Wang, Jun Zhu, Wubiao Li, Jichang |
| author_facet | Wang, Jun Zhu, Wubiao Li, Jichang |
| author_sort | Wang, Jun |
| collection | PubMed |
| description | In the title one-dimensional coordination polymer, [Mn(NCS)(3)(C(10)H(16)N(3))](n), the Mn(II) atom is coordinated by an N,N′-bidentate Schiff base and four thiocyanate ligands in a distorted octahedral N(5)S geometry. Bridging thiocyanate ligands interconnect adjacent [Mn(NCS)(2)(C(10)H(16)N(3))] units, giving rise to helical chains extending along the b axis. The chains are further linked through N—H⋯S hydrogen bonds, leading to a three-dimensional supramolecular network. |
| format | Online Article Text |
| id | pubmed-3414171 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-34141712012-08-17 catena-Poly[[(2-{[2-(dimethylammonio)ethyl]iminomethyl}pyridine-κ(2) N,N′)bis(thiocyanato-κN)manganese(II)]-μ-thiocyanato-κ(2) N:S] Wang, Jun Zhu, Wubiao Li, Jichang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title one-dimensional coordination polymer, [Mn(NCS)(3)(C(10)H(16)N(3))](n), the Mn(II) atom is coordinated by an N,N′-bidentate Schiff base and four thiocyanate ligands in a distorted octahedral N(5)S geometry. Bridging thiocyanate ligands interconnect adjacent [Mn(NCS)(2)(C(10)H(16)N(3))] units, giving rise to helical chains extending along the b axis. The chains are further linked through N—H⋯S hydrogen bonds, leading to a three-dimensional supramolecular network. International Union of Crystallography 2012-07-28 /pmc/articles/PMC3414171/ /pubmed/22904778 http://dx.doi.org/10.1107/S1600536812032874 Text en © Wang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Wang, Jun Zhu, Wubiao Li, Jichang catena-Poly[[(2-{[2-(dimethylammonio)ethyl]iminomethyl}pyridine-κ(2) N,N′)bis(thiocyanato-κN)manganese(II)]-μ-thiocyanato-κ(2) N:S] |
| title |
catena-Poly[[(2-{[2-(dimethylammonio)ethyl]iminomethyl}pyridine-κ(2)
N,N′)bis(thiocyanato-κN)manganese(II)]-μ-thiocyanato-κ(2)
N:S] |
| title_full |
catena-Poly[[(2-{[2-(dimethylammonio)ethyl]iminomethyl}pyridine-κ(2)
N,N′)bis(thiocyanato-κN)manganese(II)]-μ-thiocyanato-κ(2)
N:S] |
| title_fullStr |
catena-Poly[[(2-{[2-(dimethylammonio)ethyl]iminomethyl}pyridine-κ(2)
N,N′)bis(thiocyanato-κN)manganese(II)]-μ-thiocyanato-κ(2)
N:S] |
| title_full_unstemmed |
catena-Poly[[(2-{[2-(dimethylammonio)ethyl]iminomethyl}pyridine-κ(2)
N,N′)bis(thiocyanato-κN)manganese(II)]-μ-thiocyanato-κ(2)
N:S] |
| title_short |
catena-Poly[[(2-{[2-(dimethylammonio)ethyl]iminomethyl}pyridine-κ(2)
N,N′)bis(thiocyanato-κN)manganese(II)]-μ-thiocyanato-κ(2)
N:S] |
| title_sort | catena-poly[[(2-{[2-(dimethylammonio)ethyl]iminomethyl}pyridine-κ(2)
n,n′)bis(thiocyanato-κn)manganese(ii)]-μ-thiocyanato-κ(2)
n:s] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414171/ https://www.ncbi.nlm.nih.gov/pubmed/22904778 http://dx.doi.org/10.1107/S1600536812032874 |
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