{4,4′-Dichloro-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}copper(II)

In the title Schiff base complex, [Cu(C(19)H(18)Cl(2)N(2)O(2))], the Cu(II) ion is coordinated in a distorted square-planar environment by two N atoms and two O atoms of the tetra­dentate ligand. The dihedral angle between the benzene rings is 36.86 (14)°. In the crystal, mol­ecules are linked into...

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Autores principales: Kargar, Hadi, Kia, Reza, Ganji, Fatemeh, Mirkhani, Valiollah
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414174/
https://www.ncbi.nlm.nih.gov/pubmed/22904781
http://dx.doi.org/10.1107/S1600536812033491
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author Kargar, Hadi
Kia, Reza
Ganji, Fatemeh
Mirkhani, Valiollah
author_facet Kargar, Hadi
Kia, Reza
Ganji, Fatemeh
Mirkhani, Valiollah
author_sort Kargar, Hadi
collection PubMed
description In the title Schiff base complex, [Cu(C(19)H(18)Cl(2)N(2)O(2))], the Cu(II) ion is coordinated in a distorted square-planar environment by two N atoms and two O atoms of the tetra­dentate ligand. The dihedral angle between the benzene rings is 36.86 (14)°. In the crystal, mol­ecules are linked into inversion dimers by pairs of weak C—H⋯O hydrogen bonds. In addition, π–π [centroid–centroid distance = 3.7279 (16) Å] and weak C—H⋯π inter­actions are observed.
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spelling pubmed-34141742012-08-17 {4,4′-Dichloro-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}copper(II) Kargar, Hadi Kia, Reza Ganji, Fatemeh Mirkhani, Valiollah Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title Schiff base complex, [Cu(C(19)H(18)Cl(2)N(2)O(2))], the Cu(II) ion is coordinated in a distorted square-planar environment by two N atoms and two O atoms of the tetra­dentate ligand. The dihedral angle between the benzene rings is 36.86 (14)°. In the crystal, mol­ecules are linked into inversion dimers by pairs of weak C—H⋯O hydrogen bonds. In addition, π–π [centroid–centroid distance = 3.7279 (16) Å] and weak C—H⋯π inter­actions are observed. International Union of Crystallography 2012-07-28 /pmc/articles/PMC3414174/ /pubmed/22904781 http://dx.doi.org/10.1107/S1600536812033491 Text en © Kargar et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kargar, Hadi
Kia, Reza
Ganji, Fatemeh
Mirkhani, Valiollah
{4,4′-Dichloro-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}copper(II)
title {4,4′-Dichloro-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}copper(II)
title_full {4,4′-Dichloro-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}copper(II)
title_fullStr {4,4′-Dichloro-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}copper(II)
title_full_unstemmed {4,4′-Dichloro-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}copper(II)
title_short {4,4′-Dichloro-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}copper(II)
title_sort {4,4′-dichloro-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanylyl­idene)]diphenolato}copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414174/
https://www.ncbi.nlm.nih.gov/pubmed/22904781
http://dx.doi.org/10.1107/S1600536812033491
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