3-Acetyl-1-(2,6-dimethyl­phen­yl)thio­urea

In the title compound, C(11)H(14)N(2)OS, the two N—H bonds are anti to each other and one of them is anti to the C=S and the other is syn. Further, the amide C=S and the C=O groups are anti to each other. The dihedral angle between the benzene ring and the side chain is 83.74 (5)°. An intra­molecula...

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Detalles Bibliográficos
Autores principales: Kumar, Sharatha, Foro, Sabine, Gowda, B. Thimme
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414176/
https://www.ncbi.nlm.nih.gov/pubmed/22904783
http://dx.doi.org/10.1107/S1600536812029248
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author Kumar, Sharatha
Foro, Sabine
Gowda, B. Thimme
author_facet Kumar, Sharatha
Foro, Sabine
Gowda, B. Thimme
author_sort Kumar, Sharatha
collection PubMed
description In the title compound, C(11)H(14)N(2)OS, the two N—H bonds are anti to each other and one of them is anti to the C=S and the other is syn. Further, the amide C=S and the C=O groups are anti to each other. The dihedral angle between the benzene ring and the side chain is 83.74 (5)°. An intra­molecular N—H⋯O hydrogen bond occurs. In the crystal, mol­ecules are linked into inversion dimers by pairs of N—H⋯S inter­actions.
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spelling pubmed-34141762012-08-17 3-Acetyl-1-(2,6-dimethyl­phen­yl)thio­urea Kumar, Sharatha Foro, Sabine Gowda, B. Thimme Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(11)H(14)N(2)OS, the two N—H bonds are anti to each other and one of them is anti to the C=S and the other is syn. Further, the amide C=S and the C=O groups are anti to each other. The dihedral angle between the benzene ring and the side chain is 83.74 (5)°. An intra­molecular N—H⋯O hydrogen bond occurs. In the crystal, mol­ecules are linked into inversion dimers by pairs of N—H⋯S inter­actions. International Union of Crystallography 2012-07-04 /pmc/articles/PMC3414176/ /pubmed/22904783 http://dx.doi.org/10.1107/S1600536812029248 Text en © Kumar et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kumar, Sharatha
Foro, Sabine
Gowda, B. Thimme
3-Acetyl-1-(2,6-dimethyl­phen­yl)thio­urea
title 3-Acetyl-1-(2,6-dimethyl­phen­yl)thio­urea
title_full 3-Acetyl-1-(2,6-dimethyl­phen­yl)thio­urea
title_fullStr 3-Acetyl-1-(2,6-dimethyl­phen­yl)thio­urea
title_full_unstemmed 3-Acetyl-1-(2,6-dimethyl­phen­yl)thio­urea
title_short 3-Acetyl-1-(2,6-dimethyl­phen­yl)thio­urea
title_sort 3-acetyl-1-(2,6-dimethyl­phen­yl)thio­urea
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414176/
https://www.ncbi.nlm.nih.gov/pubmed/22904783
http://dx.doi.org/10.1107/S1600536812029248
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AT forosabine 3acetyl126dimethylphenylthiourea
AT gowdabthimme 3acetyl126dimethylphenylthiourea

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