3-Acetyl-1-(2,6-dichloro­phen­yl)thio­urea

In the title compound, C(9)H(8)Cl(2)N(2)OS, the conformation of one of the N—H bonds is anti to the C=S group and the other is anti to the C=O group. Further, the conformations of the amide C=S and the C=O group are anti to each other. The 2,6-dichloro­phenyl ring and the 3-acetyl­thio­urea side cha...

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Detalles Bibliográficos
Autores principales: Kumar, Sharatha, Foro, Sabine, Gowda, B. Thimme
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414177/
https://www.ncbi.nlm.nih.gov/pubmed/22904784
http://dx.doi.org/10.1107/S160053681202925X
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author Kumar, Sharatha
Foro, Sabine
Gowda, B. Thimme
author_facet Kumar, Sharatha
Foro, Sabine
Gowda, B. Thimme
author_sort Kumar, Sharatha
collection PubMed
description In the title compound, C(9)H(8)Cl(2)N(2)OS, the conformation of one of the N—H bonds is anti to the C=S group and the other is anti to the C=O group. Further, the conformations of the amide C=S and the C=O group are anti to each other. The 2,6-dichloro­phenyl ring and the 3-acetyl­thio­urea side chain are inclined to one another at a dihedral angle of 83.44 (5)°. An intra­molecular N—H⋯O hydrogen bond occurs. In the crystal, mol­ecules form inversion dimers through pairs of N—H⋯S hydrogen bonds.
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spelling pubmed-34141772012-08-17 3-Acetyl-1-(2,6-dichloro­phen­yl)thio­urea Kumar, Sharatha Foro, Sabine Gowda, B. Thimme Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(9)H(8)Cl(2)N(2)OS, the conformation of one of the N—H bonds is anti to the C=S group and the other is anti to the C=O group. Further, the conformations of the amide C=S and the C=O group are anti to each other. The 2,6-dichloro­phenyl ring and the 3-acetyl­thio­urea side chain are inclined to one another at a dihedral angle of 83.44 (5)°. An intra­molecular N—H⋯O hydrogen bond occurs. In the crystal, mol­ecules form inversion dimers through pairs of N—H⋯S hydrogen bonds. International Union of Crystallography 2012-07-04 /pmc/articles/PMC3414177/ /pubmed/22904784 http://dx.doi.org/10.1107/S160053681202925X Text en © Kumar et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kumar, Sharatha
Foro, Sabine
Gowda, B. Thimme
3-Acetyl-1-(2,6-dichloro­phen­yl)thio­urea
title 3-Acetyl-1-(2,6-dichloro­phen­yl)thio­urea
title_full 3-Acetyl-1-(2,6-dichloro­phen­yl)thio­urea
title_fullStr 3-Acetyl-1-(2,6-dichloro­phen­yl)thio­urea
title_full_unstemmed 3-Acetyl-1-(2,6-dichloro­phen­yl)thio­urea
title_short 3-Acetyl-1-(2,6-dichloro­phen­yl)thio­urea
title_sort 3-acetyl-1-(2,6-dichloro­phen­yl)thio­urea
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414177/
https://www.ncbi.nlm.nih.gov/pubmed/22904784
http://dx.doi.org/10.1107/S160053681202925X
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AT forosabine 3acetyl126dichlorophenylthiourea
AT gowdabthimme 3acetyl126dichlorophenylthiourea

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