N-(2-Fluoro­benz­yloxy)-1,3,5-trimethyl-2,6-diphenyl­piperidin-4-imine

In the title compound, C(27)H(29)FN(2)O, the piperidine ring has a twisted boat conformation and all ring substituents occupy equatorial positions. The dihedral angle formed between the phenyl rings is 66.71 (12)°, and the phenyl rings form dihedral angles of 46.60 (13) and 43.75 (13)° with the fluo...

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Detalles Bibliográficos
Autores principales: Ramalingan, Chennan, Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414181/
https://www.ncbi.nlm.nih.gov/pubmed/22904788
http://dx.doi.org/10.1107/S1600536812029327
Descripción
Sumario:In the title compound, C(27)H(29)FN(2)O, the piperidine ring has a twisted boat conformation and all ring substituents occupy equatorial positions. The dihedral angle formed between the phenyl rings is 66.71 (12)°, and the phenyl rings form dihedral angles of 46.60 (13) and 43.75 (13)° with the fluoro­benzene ring, which occupies a position coplanar to the meth­oxy(methyl­idene)amine residue [N—O—C—C torsion angle = −179.5 (2)°]. In the crystal, a complex network of C—H⋯π inter­actions connects the mol­ecules into a three-dimensional architecture.

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