N-(2-Fluoro­benz­yloxy)-1,3,5-trimethyl-2,6-diphenyl­piperidin-4-imine

In the title compound, C(27)H(29)FN(2)O, the piperidine ring has a twisted boat conformation and all ring substituents occupy equatorial positions. The dihedral angle formed between the phenyl rings is 66.71 (12)°, and the phenyl rings form dihedral angles of 46.60 (13) and 43.75 (13)° with the fluo...

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Detalles Bibliográficos
Autores principales: Ramalingan, Chennan, Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414181/
https://www.ncbi.nlm.nih.gov/pubmed/22904788
http://dx.doi.org/10.1107/S1600536812029327
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author Ramalingan, Chennan
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Ramalingan, Chennan
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Ramalingan, Chennan
collection PubMed
description In the title compound, C(27)H(29)FN(2)O, the piperidine ring has a twisted boat conformation and all ring substituents occupy equatorial positions. The dihedral angle formed between the phenyl rings is 66.71 (12)°, and the phenyl rings form dihedral angles of 46.60 (13) and 43.75 (13)° with the fluoro­benzene ring, which occupies a position coplanar to the meth­oxy(methyl­idene)amine residue [N—O—C—C torsion angle = −179.5 (2)°]. In the crystal, a complex network of C—H⋯π inter­actions connects the mol­ecules into a three-dimensional architecture.
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spelling pubmed-34141812012-08-17 N-(2-Fluoro­benz­yloxy)-1,3,5-trimethyl-2,6-diphenyl­piperidin-4-imine Ramalingan, Chennan Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(27)H(29)FN(2)O, the piperidine ring has a twisted boat conformation and all ring substituents occupy equatorial positions. The dihedral angle formed between the phenyl rings is 66.71 (12)°, and the phenyl rings form dihedral angles of 46.60 (13) and 43.75 (13)° with the fluoro­benzene ring, which occupies a position coplanar to the meth­oxy(methyl­idene)amine residue [N—O—C—C torsion angle = −179.5 (2)°]. In the crystal, a complex network of C—H⋯π inter­actions connects the mol­ecules into a three-dimensional architecture. International Union of Crystallography 2012-07-04 /pmc/articles/PMC3414181/ /pubmed/22904788 http://dx.doi.org/10.1107/S1600536812029327 Text en © Ramalingan et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ramalingan, Chennan
Ng, Seik Weng
Tiekink, Edward R. T.
N-(2-Fluoro­benz­yloxy)-1,3,5-trimethyl-2,6-diphenyl­piperidin-4-imine
title N-(2-Fluoro­benz­yloxy)-1,3,5-trimethyl-2,6-diphenyl­piperidin-4-imine
title_full N-(2-Fluoro­benz­yloxy)-1,3,5-trimethyl-2,6-diphenyl­piperidin-4-imine
title_fullStr N-(2-Fluoro­benz­yloxy)-1,3,5-trimethyl-2,6-diphenyl­piperidin-4-imine
title_full_unstemmed N-(2-Fluoro­benz­yloxy)-1,3,5-trimethyl-2,6-diphenyl­piperidin-4-imine
title_short N-(2-Fluoro­benz­yloxy)-1,3,5-trimethyl-2,6-diphenyl­piperidin-4-imine
title_sort n-(2-fluoro­benz­yloxy)-1,3,5-trimethyl-2,6-diphenyl­piperidin-4-imine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414181/
https://www.ncbi.nlm.nih.gov/pubmed/22904788
http://dx.doi.org/10.1107/S1600536812029327
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AT ngseikweng n2fluorobenzyloxy135trimethyl26diphenylpiperidin4imine
AT tiekinkedwardrt n2fluorobenzyloxy135trimethyl26diphenylpiperidin4imine

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