4-[3-(Pyridin-4-yl)prop­yl]pyridinium 2-carb­oxy­benzoate

In the title molecular salt, C(13)H(15)N(2) (+)·C(8)H(5)O(4) (−), the 2-carb­oxy­benzoate anions are joined into a chain along [010] by strong O—H⋯O hydrogen bonds, with the H atoms disordered about the inter­vening centres of inversion. The presence of N—H⋯O hydrogen bonds between cations generates...

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Detalles Bibliográficos
Autores principales: Xu, Wei, Qi, Jin-Li
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414185/
https://www.ncbi.nlm.nih.gov/pubmed/22904792
http://dx.doi.org/10.1107/S1600536812029339
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author Xu, Wei
Qi, Jin-Li
author_facet Xu, Wei
Qi, Jin-Li
author_sort Xu, Wei
collection PubMed
description In the title molecular salt, C(13)H(15)N(2) (+)·C(8)H(5)O(4) (−), the 2-carb­oxy­benzoate anions are joined into a chain along [010] by strong O—H⋯O hydrogen bonds, with the H atoms disordered about the inter­vening centres of inversion. The presence of N—H⋯O hydrogen bonds between cations generates an additional chain along [010] and parallel to that of the anions. The chains are assembled into a three-dimensional framework via weak C—H⋯O inter­chain inter­actions. In the cation, thee dihedral angle between the pyridine rings is 48.91 (4)°.
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spelling pubmed-34141852012-08-17 4-[3-(Pyridin-4-yl)prop­yl]pyridinium 2-carb­oxy­benzoate Xu, Wei Qi, Jin-Li Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title molecular salt, C(13)H(15)N(2) (+)·C(8)H(5)O(4) (−), the 2-carb­oxy­benzoate anions are joined into a chain along [010] by strong O—H⋯O hydrogen bonds, with the H atoms disordered about the inter­vening centres of inversion. The presence of N—H⋯O hydrogen bonds between cations generates an additional chain along [010] and parallel to that of the anions. The chains are assembled into a three-dimensional framework via weak C—H⋯O inter­chain inter­actions. In the cation, thee dihedral angle between the pyridine rings is 48.91 (4)°. International Union of Crystallography 2012-07-04 /pmc/articles/PMC3414185/ /pubmed/22904792 http://dx.doi.org/10.1107/S1600536812029339 Text en © Xu and Qi 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Xu, Wei
Qi, Jin-Li
4-[3-(Pyridin-4-yl)prop­yl]pyridinium 2-carb­oxy­benzoate
title 4-[3-(Pyridin-4-yl)prop­yl]pyridinium 2-carb­oxy­benzoate
title_full 4-[3-(Pyridin-4-yl)prop­yl]pyridinium 2-carb­oxy­benzoate
title_fullStr 4-[3-(Pyridin-4-yl)prop­yl]pyridinium 2-carb­oxy­benzoate
title_full_unstemmed 4-[3-(Pyridin-4-yl)prop­yl]pyridinium 2-carb­oxy­benzoate
title_short 4-[3-(Pyridin-4-yl)prop­yl]pyridinium 2-carb­oxy­benzoate
title_sort 4-[3-(pyridin-4-yl)prop­yl]pyridinium 2-carb­oxy­benzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414185/
https://www.ncbi.nlm.nih.gov/pubmed/22904792
http://dx.doi.org/10.1107/S1600536812029339
work_keys_str_mv AT xuwei 43pyridin4ylpropylpyridinium2carboxybenzoate
AT qijinli 43pyridin4ylpropylpyridinium2carboxybenzoate

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