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(E)-4-Amino-N′-(2-hydroxy-5-methoxybenzylidene)benzohydrazide monohydrate
In the title compound, C(15)H(15)N(3)O(3)·H(2)O, the hydazide Schiff base molecule shows an E conformation around the C=N bond. An intramolecular O—H⋯N hydrogen bond makes an S(6) ring motif. The dihedral angle between the substituted phenyl rings is 23.40 (11)°. The water molecule mediates linki...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414187/ https://www.ncbi.nlm.nih.gov/pubmed/22904794 http://dx.doi.org/10.1107/S1600536812026633 |
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author | Kargar, Hadi Kia, Reza Tahir, Muhammad Nawaz |
author_facet | Kargar, Hadi Kia, Reza Tahir, Muhammad Nawaz |
author_sort | Kargar, Hadi |
collection | PubMed |
description | In the title compound, C(15)H(15)N(3)O(3)·H(2)O, the hydazide Schiff base molecule shows an E conformation around the C=N bond. An intramolecular O—H⋯N hydrogen bond makes an S(6) ring motif. The dihedral angle between the substituted phenyl rings is 23.40 (11)°. The water molecule mediates linking of neighbouring molecules through O—H⋯(O,O) hydrogen bonds into infinite chains along the a axis, which are further connected together through N—H⋯O hydrogen bonds, forming a two-dimensional network parallel to (001). C—H⋯O interactions aso occur. |
format | Online Article Text |
id | pubmed-3414187 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-34141872012-08-17 (E)-4-Amino-N′-(2-hydroxy-5-methoxybenzylidene)benzohydrazide monohydrate Kargar, Hadi Kia, Reza Tahir, Muhammad Nawaz Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(15)H(15)N(3)O(3)·H(2)O, the hydazide Schiff base molecule shows an E conformation around the C=N bond. An intramolecular O—H⋯N hydrogen bond makes an S(6) ring motif. The dihedral angle between the substituted phenyl rings is 23.40 (11)°. The water molecule mediates linking of neighbouring molecules through O—H⋯(O,O) hydrogen bonds into infinite chains along the a axis, which are further connected together through N—H⋯O hydrogen bonds, forming a two-dimensional network parallel to (001). C—H⋯O interactions aso occur. International Union of Crystallography 2012-07-04 /pmc/articles/PMC3414187/ /pubmed/22904794 http://dx.doi.org/10.1107/S1600536812026633 Text en © Kargar et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Kargar, Hadi Kia, Reza Tahir, Muhammad Nawaz (E)-4-Amino-N′-(2-hydroxy-5-methoxybenzylidene)benzohydrazide monohydrate |
title | (E)-4-Amino-N′-(2-hydroxy-5-methoxybenzylidene)benzohydrazide monohydrate |
title_full | (E)-4-Amino-N′-(2-hydroxy-5-methoxybenzylidene)benzohydrazide monohydrate |
title_fullStr | (E)-4-Amino-N′-(2-hydroxy-5-methoxybenzylidene)benzohydrazide monohydrate |
title_full_unstemmed | (E)-4-Amino-N′-(2-hydroxy-5-methoxybenzylidene)benzohydrazide monohydrate |
title_short | (E)-4-Amino-N′-(2-hydroxy-5-methoxybenzylidene)benzohydrazide monohydrate |
title_sort | (e)-4-amino-n′-(2-hydroxy-5-methoxybenzylidene)benzohydrazide monohydrate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414187/ https://www.ncbi.nlm.nih.gov/pubmed/22904794 http://dx.doi.org/10.1107/S1600536812026633 |
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