(R (P))-5-Methyl-2-(propan-2-yl)cyclo­hexyl phen­yl{phen­yl[(1-phenyl­eth­yl)amino]­meth­yl}phosphinate

In the title compound, C(31)H(40)NO(2)P, the P atom has a distorted tetra­hedral stereochemistry [bond-angle range about P = 103.33 (6)–115.24 (15)°] and has R (P) chirality, which was confirmed crystallographically. The dihedral angles between the P-bonded phenyl ring and the other two phenyl rings...

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Detalles Bibliográficos
Autores principales: Yang, Meng, Sun, Yong-Ming, Hou, Qing-Gao, Zhao, Chang-Qiu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414267/
https://www.ncbi.nlm.nih.gov/pubmed/22904800
http://dx.doi.org/10.1107/S1600536812028243
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author Yang, Meng
Sun, Yong-Ming
Hou, Qing-Gao
Zhao, Chang-Qiu
author_facet Yang, Meng
Sun, Yong-Ming
Hou, Qing-Gao
Zhao, Chang-Qiu
author_sort Yang, Meng
collection PubMed
description In the title compound, C(31)H(40)NO(2)P, the P atom has a distorted tetra­hedral stereochemistry [bond-angle range about P = 103.33 (6)–115.24 (15)°] and has R (P) chirality, which was confirmed crystallographically. The dihedral angles between the P-bonded phenyl ring and the other two phenyl rings are 40.4 (3) and 12.2 (2)°. In the crystal, a C—H⋯O inter­action links mol­ecules into chains which extend along [100].
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spelling pubmed-34142672012-08-17 (R (P))-5-Methyl-2-(propan-2-yl)cyclo­hexyl phen­yl{phen­yl[(1-phenyl­eth­yl)amino]­meth­yl}phosphinate Yang, Meng Sun, Yong-Ming Hou, Qing-Gao Zhao, Chang-Qiu Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(31)H(40)NO(2)P, the P atom has a distorted tetra­hedral stereochemistry [bond-angle range about P = 103.33 (6)–115.24 (15)°] and has R (P) chirality, which was confirmed crystallographically. The dihedral angles between the P-bonded phenyl ring and the other two phenyl rings are 40.4 (3) and 12.2 (2)°. In the crystal, a C—H⋯O inter­action links mol­ecules into chains which extend along [100]. International Union of Crystallography 2012-07-04 /pmc/articles/PMC3414267/ /pubmed/22904800 http://dx.doi.org/10.1107/S1600536812028243 Text en © Yang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Yang, Meng
Sun, Yong-Ming
Hou, Qing-Gao
Zhao, Chang-Qiu
(R (P))-5-Methyl-2-(propan-2-yl)cyclo­hexyl phen­yl{phen­yl[(1-phenyl­eth­yl)amino]­meth­yl}phosphinate
title (R (P))-5-Methyl-2-(propan-2-yl)cyclo­hexyl phen­yl{phen­yl[(1-phenyl­eth­yl)amino]­meth­yl}phosphinate
title_full (R (P))-5-Methyl-2-(propan-2-yl)cyclo­hexyl phen­yl{phen­yl[(1-phenyl­eth­yl)amino]­meth­yl}phosphinate
title_fullStr (R (P))-5-Methyl-2-(propan-2-yl)cyclo­hexyl phen­yl{phen­yl[(1-phenyl­eth­yl)amino]­meth­yl}phosphinate
title_full_unstemmed (R (P))-5-Methyl-2-(propan-2-yl)cyclo­hexyl phen­yl{phen­yl[(1-phenyl­eth­yl)amino]­meth­yl}phosphinate
title_short (R (P))-5-Methyl-2-(propan-2-yl)cyclo­hexyl phen­yl{phen­yl[(1-phenyl­eth­yl)amino]­meth­yl}phosphinate
title_sort (r (p))-5-methyl-2-(propan-2-yl)cyclo­hexyl phen­yl{phen­yl[(1-phenyl­eth­yl)amino]­meth­yl}phosphinate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414267/
https://www.ncbi.nlm.nih.gov/pubmed/22904800
http://dx.doi.org/10.1107/S1600536812028243
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