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6-Hydroxy-7,8-dimethylchroman-2-one
The title compound, C(11)H(12)O(3), is essentially planar, with an r.m.s. deviation of 0.179 Å from the mean plane through the 14 non-H atoms in the molecule. The benzene ring and the pyranone mean plane are inclined at 13.12 (6)° to one another and the pyranone ring adopts a flattened chair confo...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414271/ https://www.ncbi.nlm.nih.gov/pubmed/22904804 http://dx.doi.org/10.1107/S1600536812029704 |
Sumario: | The title compound, C(11)H(12)O(3), is essentially planar, with an r.m.s. deviation of 0.179 Å from the mean plane through the 14 non-H atoms in the molecule. The benzene ring and the pyranone mean plane are inclined at 13.12 (6)° to one another and the pyranone ring adopts a flattened chair conformation. In the crystal, O—H⋯O hydrogen bonds and C—H⋯O contacts form R (1) (2)(6) rings and link molecules into chains along b. Additional C—H⋯O contacts generate inversion dimers, with R (2) (2)(8) ring motifs, and form sheets parallel to (-102) which are linked by C—H⋯π interactions. |
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