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N-[(2Z,4Z)-4-Benzyl­idene-6-chloro-1,4-dihydro­pyrido[2,3-d][1,3]thia­zin-2-yl­idene]benzamide

In the crystal structure of the title compound, C(21)H(14)ClN(3)OS, mol­ecules assemble into inversion dimers via pairs of N—H⋯N hydrogen bonds involving the N—H hydrogen of the thia­zine ring and the N atom of the pyridine ring. There is a close intra­molecular contact [2.570 (2) Å] between the car...

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Detalles Bibliográficos
Autores principales: Fernandes, Manuel A., Levendis, Demetrius C., Reid, David H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414281/
https://www.ncbi.nlm.nih.gov/pubmed/22904814
http://dx.doi.org/10.1107/S1600536812029741
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author Fernandes, Manuel A.
Levendis, Demetrius C.
Reid, David H.
author_facet Fernandes, Manuel A.
Levendis, Demetrius C.
Reid, David H.
author_sort Fernandes, Manuel A.
collection PubMed
description In the crystal structure of the title compound, C(21)H(14)ClN(3)OS, mol­ecules assemble into inversion dimers via pairs of N—H⋯N hydrogen bonds involving the N—H hydrogen of the thia­zine ring and the N atom of the pyridine ring. There is a close intra­molecular contact [2.570 (2) Å] between the carbonyl O atom of the benzamide and the S atom of the puckered thia­zine ring. The title compound can exist in two tautomeric forms, viz. amino or imino. The observed structure is compatible with the imino form on the basis of observed residual electron density and the two C—N bond lengths of 1.308 (2) and 1.353 (2) Å.
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spelling pubmed-34142812012-08-17 N-[(2Z,4Z)-4-Benzyl­idene-6-chloro-1,4-dihydro­pyrido[2,3-d][1,3]thia­zin-2-yl­idene]benzamide Fernandes, Manuel A. Levendis, Demetrius C. Reid, David H. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(21)H(14)ClN(3)OS, mol­ecules assemble into inversion dimers via pairs of N—H⋯N hydrogen bonds involving the N—H hydrogen of the thia­zine ring and the N atom of the pyridine ring. There is a close intra­molecular contact [2.570 (2) Å] between the carbonyl O atom of the benzamide and the S atom of the puckered thia­zine ring. The title compound can exist in two tautomeric forms, viz. amino or imino. The observed structure is compatible with the imino form on the basis of observed residual electron density and the two C—N bond lengths of 1.308 (2) and 1.353 (2) Å. International Union of Crystallography 2012-07-07 /pmc/articles/PMC3414281/ /pubmed/22904814 http://dx.doi.org/10.1107/S1600536812029741 Text en © Fernandes et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fernandes, Manuel A.
Levendis, Demetrius C.
Reid, David H.
N-[(2Z,4Z)-4-Benzyl­idene-6-chloro-1,4-dihydro­pyrido[2,3-d][1,3]thia­zin-2-yl­idene]benzamide
title N-[(2Z,4Z)-4-Benzyl­idene-6-chloro-1,4-dihydro­pyrido[2,3-d][1,3]thia­zin-2-yl­idene]benzamide
title_full N-[(2Z,4Z)-4-Benzyl­idene-6-chloro-1,4-dihydro­pyrido[2,3-d][1,3]thia­zin-2-yl­idene]benzamide
title_fullStr N-[(2Z,4Z)-4-Benzyl­idene-6-chloro-1,4-dihydro­pyrido[2,3-d][1,3]thia­zin-2-yl­idene]benzamide
title_full_unstemmed N-[(2Z,4Z)-4-Benzyl­idene-6-chloro-1,4-dihydro­pyrido[2,3-d][1,3]thia­zin-2-yl­idene]benzamide
title_short N-[(2Z,4Z)-4-Benzyl­idene-6-chloro-1,4-dihydro­pyrido[2,3-d][1,3]thia­zin-2-yl­idene]benzamide
title_sort n-[(2z,4z)-4-benzyl­idene-6-chloro-1,4-dihydro­pyrido[2,3-d][1,3]thia­zin-2-yl­idene]benzamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414281/
https://www.ncbi.nlm.nih.gov/pubmed/22904814
http://dx.doi.org/10.1107/S1600536812029741
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