(Z)-1-(4-Methyl­phen­yl)-2-(phenyl­sulfon­yl)ethanone oxime

The mol­ecule of the title compound, C(15)H(15)NO(3)S, has a twisted U-shaped conformation: the twist occurs at the central C—S(=O)(2)—C—C—C unit and the benzene ring makes a dihedral angle of 28.74 (7)° with the phenyl ring. The S—C—C=N torsion angle is −88.95 (13)°. In the crystal, inversion dimer...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Chia, Tze Shyang, Al-Rashood, Khalid A., Abdel-Aziz, Hatem A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414300/
https://www.ncbi.nlm.nih.gov/pubmed/22904833
http://dx.doi.org/10.1107/S1600536812030346
Descripción
Sumario:The mol­ecule of the title compound, C(15)H(15)NO(3)S, has a twisted U-shaped conformation: the twist occurs at the central C—S(=O)(2)—C—C—C unit and the benzene ring makes a dihedral angle of 28.74 (7)° with the phenyl ring. The S—C—C=N torsion angle is −88.95 (13)°. In the crystal, inversion dimers linked by pairs of O—H⋯N hydrogen bonds generate R (2) (2)(6) loops, and C—H⋯O hydrogen bonds connect the dimers into a three-dimensional network.

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