(Z)-1-(4-Methyl­phen­yl)-2-(phenyl­sulfon­yl)ethanone oxime

The mol­ecule of the title compound, C(15)H(15)NO(3)S, has a twisted U-shaped conformation: the twist occurs at the central C—S(=O)(2)—C—C—C unit and the benzene ring makes a dihedral angle of 28.74 (7)° with the phenyl ring. The S—C—C=N torsion angle is −88.95 (13)°. In the crystal, inversion dimer...

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Autores principales: Fun, Hoong-Kun, Chia, Tze Shyang, Al-Rashood, Khalid A., Abdel-Aziz, Hatem A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414300/
https://www.ncbi.nlm.nih.gov/pubmed/22904833
http://dx.doi.org/10.1107/S1600536812030346
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author Fun, Hoong-Kun
Chia, Tze Shyang
Al-Rashood, Khalid A.
Abdel-Aziz, Hatem A.
author_facet Fun, Hoong-Kun
Chia, Tze Shyang
Al-Rashood, Khalid A.
Abdel-Aziz, Hatem A.
author_sort Fun, Hoong-Kun
collection PubMed
description The mol­ecule of the title compound, C(15)H(15)NO(3)S, has a twisted U-shaped conformation: the twist occurs at the central C—S(=O)(2)—C—C—C unit and the benzene ring makes a dihedral angle of 28.74 (7)° with the phenyl ring. The S—C—C=N torsion angle is −88.95 (13)°. In the crystal, inversion dimers linked by pairs of O—H⋯N hydrogen bonds generate R (2) (2)(6) loops, and C—H⋯O hydrogen bonds connect the dimers into a three-dimensional network.
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spelling pubmed-34143002012-08-17 (Z)-1-(4-Methyl­phen­yl)-2-(phenyl­sulfon­yl)ethanone oxime Fun, Hoong-Kun Chia, Tze Shyang Al-Rashood, Khalid A. Abdel-Aziz, Hatem A. Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title compound, C(15)H(15)NO(3)S, has a twisted U-shaped conformation: the twist occurs at the central C—S(=O)(2)—C—C—C unit and the benzene ring makes a dihedral angle of 28.74 (7)° with the phenyl ring. The S—C—C=N torsion angle is −88.95 (13)°. In the crystal, inversion dimers linked by pairs of O—H⋯N hydrogen bonds generate R (2) (2)(6) loops, and C—H⋯O hydrogen bonds connect the dimers into a three-dimensional network. International Union of Crystallography 2012-07-07 /pmc/articles/PMC3414300/ /pubmed/22904833 http://dx.doi.org/10.1107/S1600536812030346 Text en © Fun et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Chia, Tze Shyang
Al-Rashood, Khalid A.
Abdel-Aziz, Hatem A.
(Z)-1-(4-Methyl­phen­yl)-2-(phenyl­sulfon­yl)ethanone oxime
title (Z)-1-(4-Methyl­phen­yl)-2-(phenyl­sulfon­yl)ethanone oxime
title_full (Z)-1-(4-Methyl­phen­yl)-2-(phenyl­sulfon­yl)ethanone oxime
title_fullStr (Z)-1-(4-Methyl­phen­yl)-2-(phenyl­sulfon­yl)ethanone oxime
title_full_unstemmed (Z)-1-(4-Methyl­phen­yl)-2-(phenyl­sulfon­yl)ethanone oxime
title_short (Z)-1-(4-Methyl­phen­yl)-2-(phenyl­sulfon­yl)ethanone oxime
title_sort (z)-1-(4-methyl­phen­yl)-2-(phenyl­sulfon­yl)ethanone oxime
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414300/
https://www.ncbi.nlm.nih.gov/pubmed/22904833
http://dx.doi.org/10.1107/S1600536812030346
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