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(2E)-1-(4,4′′-Difluoro-5′-methoxy-1,1′:3′,1′′-terphenyl-4′-yl)-3-[4-(methylsulfanyl)phenyl]prop-2-en-1-one
In the title compound, C(29)H(22)F(2)O(2)S, the central benzene ring makes dihedral angles of 45.83 (7), 38.90 (7) and 55.50 (7)° with the two fluoro-substituted benzene rings and the methylsulfanyl-substituted benzene ring, respectively. In the crystal, C—H⋯O contacts connect the molecules into l...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414306/ https://www.ncbi.nlm.nih.gov/pubmed/22904839 http://dx.doi.org/10.1107/S1600536812030139 |
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author | Kant, Rajni Gupta, Vivek K. Kapoor, Kamini Samshuddin, S. Narayana, B. |
author_facet | Kant, Rajni Gupta, Vivek K. Kapoor, Kamini Samshuddin, S. Narayana, B. |
author_sort | Kant, Rajni |
collection | PubMed |
description | In the title compound, C(29)H(22)F(2)O(2)S, the central benzene ring makes dihedral angles of 45.83 (7), 38.90 (7) and 55.50 (7)° with the two fluoro-substituted benzene rings and the methylsulfanyl-substituted benzene ring, respectively. In the crystal, C—H⋯O contacts connect the molecules into layers lying perpendicular to the c axis. In addition, π–π stacking interactions between one of the fluorophenyl groups [centroid–centroid distances = 3.681 (1) and 3.818 (1) Å] are observed. |
format | Online Article Text |
id | pubmed-3414306 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-34143062012-08-17 (2E)-1-(4,4′′-Difluoro-5′-methoxy-1,1′:3′,1′′-terphenyl-4′-yl)-3-[4-(methylsulfanyl)phenyl]prop-2-en-1-one Kant, Rajni Gupta, Vivek K. Kapoor, Kamini Samshuddin, S. Narayana, B. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(29)H(22)F(2)O(2)S, the central benzene ring makes dihedral angles of 45.83 (7), 38.90 (7) and 55.50 (7)° with the two fluoro-substituted benzene rings and the methylsulfanyl-substituted benzene ring, respectively. In the crystal, C—H⋯O contacts connect the molecules into layers lying perpendicular to the c axis. In addition, π–π stacking interactions between one of the fluorophenyl groups [centroid–centroid distances = 3.681 (1) and 3.818 (1) Å] are observed. International Union of Crystallography 2012-07-07 /pmc/articles/PMC3414306/ /pubmed/22904839 http://dx.doi.org/10.1107/S1600536812030139 Text en © Kant et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Kant, Rajni Gupta, Vivek K. Kapoor, Kamini Samshuddin, S. Narayana, B. (2E)-1-(4,4′′-Difluoro-5′-methoxy-1,1′:3′,1′′-terphenyl-4′-yl)-3-[4-(methylsulfanyl)phenyl]prop-2-en-1-one |
title | (2E)-1-(4,4′′-Difluoro-5′-methoxy-1,1′:3′,1′′-terphenyl-4′-yl)-3-[4-(methylsulfanyl)phenyl]prop-2-en-1-one |
title_full | (2E)-1-(4,4′′-Difluoro-5′-methoxy-1,1′:3′,1′′-terphenyl-4′-yl)-3-[4-(methylsulfanyl)phenyl]prop-2-en-1-one |
title_fullStr | (2E)-1-(4,4′′-Difluoro-5′-methoxy-1,1′:3′,1′′-terphenyl-4′-yl)-3-[4-(methylsulfanyl)phenyl]prop-2-en-1-one |
title_full_unstemmed | (2E)-1-(4,4′′-Difluoro-5′-methoxy-1,1′:3′,1′′-terphenyl-4′-yl)-3-[4-(methylsulfanyl)phenyl]prop-2-en-1-one |
title_short | (2E)-1-(4,4′′-Difluoro-5′-methoxy-1,1′:3′,1′′-terphenyl-4′-yl)-3-[4-(methylsulfanyl)phenyl]prop-2-en-1-one |
title_sort | (2e)-1-(4,4′′-difluoro-5′-methoxy-1,1′:3′,1′′-terphenyl-4′-yl)-3-[4-(methylsulfanyl)phenyl]prop-2-en-1-one |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414306/ https://www.ncbi.nlm.nih.gov/pubmed/22904839 http://dx.doi.org/10.1107/S1600536812030139 |
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