N-Benzoyl-N-(1,4-dioxonaphthalen-2-yl)benzamide

The title mol­ecule, C(24)H(15)NO(4), crystallizes with two mol­ecules in the asymmetric unit (Z′ = 2). For both mol­ecules, the two amide groups are not coplanar, as the dihedral angles of the respective NCO groups are similar at 50.37 (14) and 51.22 (13)°. However, the orientations of the substitu...

Descripción completa

Detalles Bibliográficos
Autores principales: Brandy, Yakini, Butcher, Ray J., Bakare, Oladapo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414307/
https://www.ncbi.nlm.nih.gov/pubmed/22904840
http://dx.doi.org/10.1107/S1600536812030231
Descripción
Sumario:The title mol­ecule, C(24)H(15)NO(4), crystallizes with two mol­ecules in the asymmetric unit (Z′ = 2). For both mol­ecules, the two amide groups are not coplanar, as the dihedral angles of the respective NCO groups are similar at 50.37 (14) and 51.22 (13)°. However, the orientations of the substituent phenyl rings with the central naphthalene system are significantly different for the two mol­ecules; for one mol­ecule, these dihedral angles are 80.29 (3) and 80.95 (4)°, while for the second mol­ecule they are 86.63 (3) and 72.82 (4)°. The crystal packing shows the mol­ecules to be linked by weak C—H⋯O inter­actions.

Ejemplares similares