N-Benzoyl-N-(1,4-dioxonaphthalen-2-yl)benzamide

The title mol­ecule, C(24)H(15)NO(4), crystallizes with two mol­ecules in the asymmetric unit (Z′ = 2). For both mol­ecules, the two amide groups are not coplanar, as the dihedral angles of the respective NCO groups are similar at 50.37 (14) and 51.22 (13)°. However, the orientations of the substitu...

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Detalles Bibliográficos
Autores principales: Brandy, Yakini, Butcher, Ray J., Bakare, Oladapo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414307/
https://www.ncbi.nlm.nih.gov/pubmed/22904840
http://dx.doi.org/10.1107/S1600536812030231
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author Brandy, Yakini
Butcher, Ray J.
Bakare, Oladapo
author_facet Brandy, Yakini
Butcher, Ray J.
Bakare, Oladapo
author_sort Brandy, Yakini
collection PubMed
description The title mol­ecule, C(24)H(15)NO(4), crystallizes with two mol­ecules in the asymmetric unit (Z′ = 2). For both mol­ecules, the two amide groups are not coplanar, as the dihedral angles of the respective NCO groups are similar at 50.37 (14) and 51.22 (13)°. However, the orientations of the substituent phenyl rings with the central naphthalene system are significantly different for the two mol­ecules; for one mol­ecule, these dihedral angles are 80.29 (3) and 80.95 (4)°, while for the second mol­ecule they are 86.63 (3) and 72.82 (4)°. The crystal packing shows the mol­ecules to be linked by weak C—H⋯O inter­actions.
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spelling pubmed-34143072012-08-17 N-Benzoyl-N-(1,4-dioxonaphthalen-2-yl)benzamide Brandy, Yakini Butcher, Ray J. Bakare, Oladapo Acta Crystallogr Sect E Struct Rep Online Organic Papers The title mol­ecule, C(24)H(15)NO(4), crystallizes with two mol­ecules in the asymmetric unit (Z′ = 2). For both mol­ecules, the two amide groups are not coplanar, as the dihedral angles of the respective NCO groups are similar at 50.37 (14) and 51.22 (13)°. However, the orientations of the substituent phenyl rings with the central naphthalene system are significantly different for the two mol­ecules; for one mol­ecule, these dihedral angles are 80.29 (3) and 80.95 (4)°, while for the second mol­ecule they are 86.63 (3) and 72.82 (4)°. The crystal packing shows the mol­ecules to be linked by weak C—H⋯O inter­actions. International Union of Crystallography 2012-07-07 /pmc/articles/PMC3414307/ /pubmed/22904840 http://dx.doi.org/10.1107/S1600536812030231 Text en © Brandy et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Brandy, Yakini
Butcher, Ray J.
Bakare, Oladapo
N-Benzoyl-N-(1,4-dioxonaphthalen-2-yl)benzamide
title N-Benzoyl-N-(1,4-dioxonaphthalen-2-yl)benzamide
title_full N-Benzoyl-N-(1,4-dioxonaphthalen-2-yl)benzamide
title_fullStr N-Benzoyl-N-(1,4-dioxonaphthalen-2-yl)benzamide
title_full_unstemmed N-Benzoyl-N-(1,4-dioxonaphthalen-2-yl)benzamide
title_short N-Benzoyl-N-(1,4-dioxonaphthalen-2-yl)benzamide
title_sort n-benzoyl-n-(1,4-dioxonaphthalen-2-yl)benzamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414307/
https://www.ncbi.nlm.nih.gov/pubmed/22904840
http://dx.doi.org/10.1107/S1600536812030231
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