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Bis(tetra­ethyl­ammonium) oxalate dihydrate

The title compound, 2C(8)H(20)N(+)·C(2)O(4) (2−)·2H(2)O, synthesized by neutralizing H(2)C(2)O(4)·2H(2)O with (C(2)H(5))(4)NOH in a 1:2 molar ratio, is a deliquescent solid. The oxalate ion is nonplanar, with a dihedral angle between carboxyl­ate groups of 64.37 (2)°. O—H⋯O hydrogen bonds of moderat...

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Detalles Bibliográficos
Autores principales: McNeese, Timothy J., Pike, Robert D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414309/
https://www.ncbi.nlm.nih.gov/pubmed/22904842
http://dx.doi.org/10.1107/S160053681203022X
Descripción
Sumario:The title compound, 2C(8)H(20)N(+)·C(2)O(4) (2−)·2H(2)O, synthesized by neutralizing H(2)C(2)O(4)·2H(2)O with (C(2)H(5))(4)NOH in a 1:2 molar ratio, is a deliquescent solid. The oxalate ion is nonplanar, with a dihedral angle between carboxyl­ate groups of 64.37 (2)°. O—H⋯O hydrogen bonds of moderate strength link the O atoms of the water mol­ecules and the oxalate ions into rings parallel to the c axis. The rings exhibit the graph-set motif R (4) (4)(12). In addition, there are weak C—H⋯O inter­actions in the crystal structure.