2,2′-(Piperazine-1,4-di­yl)diethanaminium bis­(2-hy­droxy­benzoate)

The asymmetric unit of the title salt, C(8)H(22)N(4) (2+)·2C(7)H(5)O(3) (−), comprises half a 2,2′-(piperazine-1,4-di­yl)diethan­aminium dication plus a 2-hy­droxy­benzoate anion. In the crystal, the anions and cations are linked by N—H⋯O and O—H⋯O hydrogen bonds to form infinite two-dimensional net...

Descripción completa

Detalles Bibliográficos
Autores principales: Cukrowski, Ignacy, Adeyinka, Adedapo S., Liles, David C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414313/
https://www.ncbi.nlm.nih.gov/pubmed/22904846
http://dx.doi.org/10.1107/S1600536812030103
_version_ 1782240190713036800
author Cukrowski, Ignacy
Adeyinka, Adedapo S.
Liles, David C.
author_facet Cukrowski, Ignacy
Adeyinka, Adedapo S.
Liles, David C.
author_sort Cukrowski, Ignacy
collection PubMed
description The asymmetric unit of the title salt, C(8)H(22)N(4) (2+)·2C(7)H(5)O(3) (−), comprises half a 2,2′-(piperazine-1,4-di­yl)diethan­aminium dication plus a 2-hy­droxy­benzoate anion. In the crystal, the anions and cations are linked by N—H⋯O and O—H⋯O hydrogen bonds to form infinite two-dimensional networks parallel with the a unit-cell face. The conformation adopted by the cation in the crystal is very similar to that adopted by the same cation in the structures of the nitrate and tetra­hydrogen penta­borate salts.
format Online
Article
Text
id pubmed-3414313
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-34143132012-08-17 2,2′-(Piperazine-1,4-di­yl)diethanaminium bis­(2-hy­droxy­benzoate) Cukrowski, Ignacy Adeyinka, Adedapo S. Liles, David C. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title salt, C(8)H(22)N(4) (2+)·2C(7)H(5)O(3) (−), comprises half a 2,2′-(piperazine-1,4-di­yl)diethan­aminium dication plus a 2-hy­droxy­benzoate anion. In the crystal, the anions and cations are linked by N—H⋯O and O—H⋯O hydrogen bonds to form infinite two-dimensional networks parallel with the a unit-cell face. The conformation adopted by the cation in the crystal is very similar to that adopted by the same cation in the structures of the nitrate and tetra­hydrogen penta­borate salts. International Union of Crystallography 2012-07-07 /pmc/articles/PMC3414313/ /pubmed/22904846 http://dx.doi.org/10.1107/S1600536812030103 Text en © Cukrowski et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Cukrowski, Ignacy
Adeyinka, Adedapo S.
Liles, David C.
2,2′-(Piperazine-1,4-di­yl)diethanaminium bis­(2-hy­droxy­benzoate)
title 2,2′-(Piperazine-1,4-di­yl)diethanaminium bis­(2-hy­droxy­benzoate)
title_full 2,2′-(Piperazine-1,4-di­yl)diethanaminium bis­(2-hy­droxy­benzoate)
title_fullStr 2,2′-(Piperazine-1,4-di­yl)diethanaminium bis­(2-hy­droxy­benzoate)
title_full_unstemmed 2,2′-(Piperazine-1,4-di­yl)diethanaminium bis­(2-hy­droxy­benzoate)
title_short 2,2′-(Piperazine-1,4-di­yl)diethanaminium bis­(2-hy­droxy­benzoate)
title_sort 2,2′-(piperazine-1,4-di­yl)diethanaminium bis­(2-hy­droxy­benzoate)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414313/
https://www.ncbi.nlm.nih.gov/pubmed/22904846
http://dx.doi.org/10.1107/S1600536812030103
work_keys_str_mv AT cukrowskiignacy 22piperazine14diyldiethanaminiumbis2hydroxybenzoate
AT adeyinkaadedapos 22piperazine14diyldiethanaminiumbis2hydroxybenzoate
AT lilesdavidc 22piperazine14diyldiethanaminiumbis2hydroxybenzoate

Ejemplares similares