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Methyl 2,6-diphenyl-1-p-tolyl-4-(p-tolylamino)-1,2,5,6-tetrahydropyridine-3-carboxylate
In the title compound, C(33)H(32)N(2)O(2), the tetrahydropyridine ring adopts a boat conformation with the carbonyl group in an s-cis conformation with respect to the C=C bond of the six-membered tetrahydropyridine ring. The molecular conformation is stabilized by intramolecular N—H⋯O, C—H⋯O a...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414317/ https://www.ncbi.nlm.nih.gov/pubmed/22904850 http://dx.doi.org/10.1107/S1600536812030309 |
Sumario: | In the title compound, C(33)H(32)N(2)O(2), the tetrahydropyridine ring adopts a boat conformation with the carbonyl group in an s-cis conformation with respect to the C=C bond of the six-membered tetrahydropyridine ring. The molecular conformation is stabilized by intramolecular N—H⋯O, C—H⋯O and C—H⋯π interactions. Formation of centrosymmetric head-to-head dimers is observed through pairwise intermolecular N—H⋯O hydrogen bonds. Additional weak C—H⋯O and C—H⋯π interactions stabilize the three-dimensional molecular assembly. |
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