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Methyl 2,6-diphenyl-1-p-tolyl-4-(p-tolylamino)-1,2,5,6-tetrahydropyridine-3-carboxylate
In the title compound, C(33)H(32)N(2)O(2), the tetrahydropyridine ring adopts a boat conformation with the carbonyl group in an s-cis conformation with respect to the C=C bond of the six-membered tetrahydropyridine ring. The molecular conformation is stabilized by intramolecular N—H⋯O, C—H⋯O a...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414317/ https://www.ncbi.nlm.nih.gov/pubmed/22904850 http://dx.doi.org/10.1107/S1600536812030309 |
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author | Venugopala, K. N. Nayak, Susanta K. Odhav, Bharti |
author_facet | Venugopala, K. N. Nayak, Susanta K. Odhav, Bharti |
author_sort | Venugopala, K. N. |
collection | PubMed |
description | In the title compound, C(33)H(32)N(2)O(2), the tetrahydropyridine ring adopts a boat conformation with the carbonyl group in an s-cis conformation with respect to the C=C bond of the six-membered tetrahydropyridine ring. The molecular conformation is stabilized by intramolecular N—H⋯O, C—H⋯O and C—H⋯π interactions. Formation of centrosymmetric head-to-head dimers is observed through pairwise intermolecular N—H⋯O hydrogen bonds. Additional weak C—H⋯O and C—H⋯π interactions stabilize the three-dimensional molecular assembly. |
format | Online Article Text |
id | pubmed-3414317 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-34143172012-08-17 Methyl 2,6-diphenyl-1-p-tolyl-4-(p-tolylamino)-1,2,5,6-tetrahydropyridine-3-carboxylate Venugopala, K. N. Nayak, Susanta K. Odhav, Bharti Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(33)H(32)N(2)O(2), the tetrahydropyridine ring adopts a boat conformation with the carbonyl group in an s-cis conformation with respect to the C=C bond of the six-membered tetrahydropyridine ring. The molecular conformation is stabilized by intramolecular N—H⋯O, C—H⋯O and C—H⋯π interactions. Formation of centrosymmetric head-to-head dimers is observed through pairwise intermolecular N—H⋯O hydrogen bonds. Additional weak C—H⋯O and C—H⋯π interactions stabilize the three-dimensional molecular assembly. International Union of Crystallography 2012-07-07 /pmc/articles/PMC3414317/ /pubmed/22904850 http://dx.doi.org/10.1107/S1600536812030309 Text en © Venugopala et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Venugopala, K. N. Nayak, Susanta K. Odhav, Bharti Methyl 2,6-diphenyl-1-p-tolyl-4-(p-tolylamino)-1,2,5,6-tetrahydropyridine-3-carboxylate |
title | Methyl 2,6-diphenyl-1-p-tolyl-4-(p-tolylamino)-1,2,5,6-tetrahydropyridine-3-carboxylate |
title_full | Methyl 2,6-diphenyl-1-p-tolyl-4-(p-tolylamino)-1,2,5,6-tetrahydropyridine-3-carboxylate |
title_fullStr | Methyl 2,6-diphenyl-1-p-tolyl-4-(p-tolylamino)-1,2,5,6-tetrahydropyridine-3-carboxylate |
title_full_unstemmed | Methyl 2,6-diphenyl-1-p-tolyl-4-(p-tolylamino)-1,2,5,6-tetrahydropyridine-3-carboxylate |
title_short | Methyl 2,6-diphenyl-1-p-tolyl-4-(p-tolylamino)-1,2,5,6-tetrahydropyridine-3-carboxylate |
title_sort | methyl 2,6-diphenyl-1-p-tolyl-4-(p-tolylamino)-1,2,5,6-tetrahydropyridine-3-carboxylate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414317/ https://www.ncbi.nlm.nih.gov/pubmed/22904850 http://dx.doi.org/10.1107/S1600536812030309 |
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