Cargando…
4-(Diphenylamino)benzaldehyde 4-phenylthiosemicarbazone
The title molecule, C(26)H(22)N(4)S, is composed of three main parts, viz. a triphenylamine group is connected to a phenyl ring by a thiosemicarbazone moiety. The C= N double bond has an E conformation. The crystal packing is dominated by strong hydrogen bonds through the thiosemicarbazone moiet...
Autores principales: | , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414326/ https://www.ncbi.nlm.nih.gov/pubmed/22904859 http://dx.doi.org/10.1107/S160053681203053X |
_version_ | 1782240193684701184 |
---|---|
author | Mendoza-Meroño, Rafael Menéndez-Taboada, Laura García-Granda, Santiago |
author_facet | Mendoza-Meroño, Rafael Menéndez-Taboada, Laura García-Granda, Santiago |
author_sort | Mendoza-Meroño, Rafael |
collection | PubMed |
description | The title molecule, C(26)H(22)N(4)S, is composed of three main parts, viz. a triphenylamine group is connected to a phenyl ring by a thiosemicarbazone moiety. The C= N double bond has an E conformation. The crystal packing is dominated by strong hydrogen bonds through the thiosemicarbazone moiety, with pairs of N—H⋯S hydrogen bonds linking the molecules to form inversion dimers with an R (2) (2)(8) ring motif. An intramolecular N—H⋯N hydrogen bond is also present, generating an S(5) ring motif. Although the structure contains four phenyl rings, π–π stacking interactions are not formed between them, probably due to the conformation adopted by the triphenylamine group. However, a weak π–π stacking interaction is observed between the phenyl ring and the delocalized thiosemicarbazone moiety. |
format | Online Article Text |
id | pubmed-3414326 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-34143262012-08-17 4-(Diphenylamino)benzaldehyde 4-phenylthiosemicarbazone Mendoza-Meroño, Rafael Menéndez-Taboada, Laura García-Granda, Santiago Acta Crystallogr Sect E Struct Rep Online Organic Papers The title molecule, C(26)H(22)N(4)S, is composed of three main parts, viz. a triphenylamine group is connected to a phenyl ring by a thiosemicarbazone moiety. The C= N double bond has an E conformation. The crystal packing is dominated by strong hydrogen bonds through the thiosemicarbazone moiety, with pairs of N—H⋯S hydrogen bonds linking the molecules to form inversion dimers with an R (2) (2)(8) ring motif. An intramolecular N—H⋯N hydrogen bond is also present, generating an S(5) ring motif. Although the structure contains four phenyl rings, π–π stacking interactions are not formed between them, probably due to the conformation adopted by the triphenylamine group. However, a weak π–π stacking interaction is observed between the phenyl ring and the delocalized thiosemicarbazone moiety. International Union of Crystallography 2012-07-10 /pmc/articles/PMC3414326/ /pubmed/22904859 http://dx.doi.org/10.1107/S160053681203053X Text en © Mendoza-Meroño et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Mendoza-Meroño, Rafael Menéndez-Taboada, Laura García-Granda, Santiago 4-(Diphenylamino)benzaldehyde 4-phenylthiosemicarbazone |
title | 4-(Diphenylamino)benzaldehyde 4-phenylthiosemicarbazone |
title_full | 4-(Diphenylamino)benzaldehyde 4-phenylthiosemicarbazone |
title_fullStr | 4-(Diphenylamino)benzaldehyde 4-phenylthiosemicarbazone |
title_full_unstemmed | 4-(Diphenylamino)benzaldehyde 4-phenylthiosemicarbazone |
title_short | 4-(Diphenylamino)benzaldehyde 4-phenylthiosemicarbazone |
title_sort | 4-(diphenylamino)benzaldehyde 4-phenylthiosemicarbazone |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414326/ https://www.ncbi.nlm.nih.gov/pubmed/22904859 http://dx.doi.org/10.1107/S160053681203053X |
work_keys_str_mv | AT mendozameronorafael 4diphenylaminobenzaldehyde4phenylthiosemicarbazone AT menendeztaboadalaura 4diphenylaminobenzaldehyde4phenylthiosemicarbazone AT garciagrandasantiago 4diphenylaminobenzaldehyde4phenylthiosemicarbazone |