N′-(2,4-Dinitro­phen­yl)benzohydrazide

In the title compound, C(13)H(10)N(4)O(5), the aromatic ring planes are close to perpendicular [dihedral angle = 75.94 (5)°] and the C—N—N—C torsion angle is 88.7 (2)°. Both nitro groups lie close to their attached ring plane, with C—C—N—O torsion angles of 3.1 (2) and 5.3 (2)°. This allows for the...

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Detalles Bibliográficos
Autores principales: Saeed, Aamer, Arshad, Ifzan, Flörke, Ulrich
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414336/
https://www.ncbi.nlm.nih.gov/pubmed/22904869
http://dx.doi.org/10.1107/S1600536812030619
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author Saeed, Aamer
Arshad, Ifzan
Flörke, Ulrich
author_facet Saeed, Aamer
Arshad, Ifzan
Flörke, Ulrich
author_sort Saeed, Aamer
collection PubMed
description In the title compound, C(13)H(10)N(4)O(5), the aromatic ring planes are close to perpendicular [dihedral angle = 75.94 (5)°] and the C—N—N—C torsion angle is 88.7 (2)°. Both nitro groups lie close to their attached ring plane, with C—C—N—O torsion angles of 3.1 (2) and 5.3 (2)°. This allows for the formation of an intra­molecular N—H⋯O hydrogen bond, which closes an S(6) ring. In the crystal, N—H⋯O hydrogen bonds link the mol­ecules into zigzag chains extending along [100].
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spelling pubmed-34143362012-08-17 N′-(2,4-Dinitro­phen­yl)benzohydrazide Saeed, Aamer Arshad, Ifzan Flörke, Ulrich Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(13)H(10)N(4)O(5), the aromatic ring planes are close to perpendicular [dihedral angle = 75.94 (5)°] and the C—N—N—C torsion angle is 88.7 (2)°. Both nitro groups lie close to their attached ring plane, with C—C—N—O torsion angles of 3.1 (2) and 5.3 (2)°. This allows for the formation of an intra­molecular N—H⋯O hydrogen bond, which closes an S(6) ring. In the crystal, N—H⋯O hydrogen bonds link the mol­ecules into zigzag chains extending along [100]. International Union of Crystallography 2012-07-10 /pmc/articles/PMC3414336/ /pubmed/22904869 http://dx.doi.org/10.1107/S1600536812030619 Text en © Saeed et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Saeed, Aamer
Arshad, Ifzan
Flörke, Ulrich
N′-(2,4-Dinitro­phen­yl)benzohydrazide
title N′-(2,4-Dinitro­phen­yl)benzohydrazide
title_full N′-(2,4-Dinitro­phen­yl)benzohydrazide
title_fullStr N′-(2,4-Dinitro­phen­yl)benzohydrazide
title_full_unstemmed N′-(2,4-Dinitro­phen­yl)benzohydrazide
title_short N′-(2,4-Dinitro­phen­yl)benzohydrazide
title_sort n′-(2,4-dinitro­phen­yl)benzohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414336/
https://www.ncbi.nlm.nih.gov/pubmed/22904869
http://dx.doi.org/10.1107/S1600536812030619
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AT arshadifzan n24dinitrophenylbenzohydrazide
AT florkeulrich n24dinitrophenylbenzohydrazide

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