N-(2,3-Dihydro-1,4-benzodioxin-6-yl)-4-fluoro­benzene­sulfonamide

In the title compound, C(14)H(12)FNO(4)S, the dihedral angle between the aromatic rings is 50.26 (9)° and the C—S—N—C bond adopts a gauche conformation [torsion angle = −68.12 (15)°]. The dihydro­dioxine ring is disordered over two orientations, which both approximate to half-chairs, in a 0.880 (7):...

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Autores principales: Mughal, Shumaila Younas, Khan, Islam Ullah, Harrison, William T. A., Khan, Muneeb Hayat, Arshad, Muhammad Nadeem
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414348/
https://www.ncbi.nlm.nih.gov/pubmed/22904881
http://dx.doi.org/10.1107/S1600536812030863
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author Mughal, Shumaila Younas
Khan, Islam Ullah
Harrison, William T. A.
Khan, Muneeb Hayat
Arshad, Muhammad Nadeem
author_facet Mughal, Shumaila Younas
Khan, Islam Ullah
Harrison, William T. A.
Khan, Muneeb Hayat
Arshad, Muhammad Nadeem
author_sort Mughal, Shumaila Younas
collection PubMed
description In the title compound, C(14)H(12)FNO(4)S, the dihedral angle between the aromatic rings is 50.26 (9)° and the C—S—N—C bond adopts a gauche conformation [torsion angle = −68.12 (15)°]. The dihydro­dioxine ring is disordered over two orientations, which both approximate to half-chairs, in a 0.880 (7):0.120 (7) ratio. In the crystal, N—H⋯O hydrogen bonds link the mol­ecules into C(4) chains propagating in [100]. Weak C—H⋯O and C—H⋯F inter­actions consolidate the packing.
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spelling pubmed-34143482012-08-17 N-(2,3-Dihydro-1,4-benzodioxin-6-yl)-4-fluoro­benzene­sulfonamide Mughal, Shumaila Younas Khan, Islam Ullah Harrison, William T. A. Khan, Muneeb Hayat Arshad, Muhammad Nadeem Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(12)FNO(4)S, the dihedral angle between the aromatic rings is 50.26 (9)° and the C—S—N—C bond adopts a gauche conformation [torsion angle = −68.12 (15)°]. The dihydro­dioxine ring is disordered over two orientations, which both approximate to half-chairs, in a 0.880 (7):0.120 (7) ratio. In the crystal, N—H⋯O hydrogen bonds link the mol­ecules into C(4) chains propagating in [100]. Weak C—H⋯O and C—H⋯F inter­actions consolidate the packing. International Union of Crystallography 2012-07-10 /pmc/articles/PMC3414348/ /pubmed/22904881 http://dx.doi.org/10.1107/S1600536812030863 Text en © Mughal et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Mughal, Shumaila Younas
Khan, Islam Ullah
Harrison, William T. A.
Khan, Muneeb Hayat
Arshad, Muhammad Nadeem
N-(2,3-Dihydro-1,4-benzodioxin-6-yl)-4-fluoro­benzene­sulfonamide
title N-(2,3-Dihydro-1,4-benzodioxin-6-yl)-4-fluoro­benzene­sulfonamide
title_full N-(2,3-Dihydro-1,4-benzodioxin-6-yl)-4-fluoro­benzene­sulfonamide
title_fullStr N-(2,3-Dihydro-1,4-benzodioxin-6-yl)-4-fluoro­benzene­sulfonamide
title_full_unstemmed N-(2,3-Dihydro-1,4-benzodioxin-6-yl)-4-fluoro­benzene­sulfonamide
title_short N-(2,3-Dihydro-1,4-benzodioxin-6-yl)-4-fluoro­benzene­sulfonamide
title_sort n-(2,3-dihydro-1,4-benzodioxin-6-yl)-4-fluoro­benzene­sulfonamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414348/
https://www.ncbi.nlm.nih.gov/pubmed/22904881
http://dx.doi.org/10.1107/S1600536812030863
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