1-(6-Fluoro-1,3-benzothia­zol-2-yl)-2-(1-phenyl­ethyl­idene)hydrazine

The asymmetric unit of the title compound, C(15)H(12)FN(3)S, consists of two independent mol­ecules with comparable geometries. In one mol­ecule, the 1,3-benzothia­zole ring system (r.m.s. deviation = 0.011 Å) forms a dihedral angle of 19.86 (6)° with the phenyl ring. The corresponding r.m.s. deviat...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Quah, Ching Kheng, Munirajasekhar, D., Himaja, M., Sarojini, B. K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414353/
https://www.ncbi.nlm.nih.gov/pubmed/22904886
http://dx.doi.org/10.1107/S1600536812030851
Descripción
Sumario:The asymmetric unit of the title compound, C(15)H(12)FN(3)S, consists of two independent mol­ecules with comparable geometries. In one mol­ecule, the 1,3-benzothia­zole ring system (r.m.s. deviation = 0.011 Å) forms a dihedral angle of 19.86 (6)° with the phenyl ring. The corresponding r.m.s. deviation and dihedral angle for the other mol­ecule are 0.014 Å and 22.32 (6)°, respectively. In the crystal, mol­ecules are linked via N—H⋯N, C—H⋯F and C—H⋯N hydrogen bonds into a three-dimensional network. The crystal studied was a non-merohedral twin with a refined BASF value of 0.301 (2).

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