1-(6-Fluoro-1,3-benzothia­zol-2-yl)-2-(1-phenyl­ethyl­idene)hydrazine

The asymmetric unit of the title compound, C(15)H(12)FN(3)S, consists of two independent mol­ecules with comparable geometries. In one mol­ecule, the 1,3-benzothia­zole ring system (r.m.s. deviation = 0.011 Å) forms a dihedral angle of 19.86 (6)° with the phenyl ring. The corresponding r.m.s. deviat...

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Autores principales: Fun, Hoong-Kun, Quah, Ching Kheng, Munirajasekhar, D., Himaja, M., Sarojini, B. K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414353/
https://www.ncbi.nlm.nih.gov/pubmed/22904886
http://dx.doi.org/10.1107/S1600536812030851
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author Fun, Hoong-Kun
Quah, Ching Kheng
Munirajasekhar, D.
Himaja, M.
Sarojini, B. K.
author_facet Fun, Hoong-Kun
Quah, Ching Kheng
Munirajasekhar, D.
Himaja, M.
Sarojini, B. K.
author_sort Fun, Hoong-Kun
collection PubMed
description The asymmetric unit of the title compound, C(15)H(12)FN(3)S, consists of two independent mol­ecules with comparable geometries. In one mol­ecule, the 1,3-benzothia­zole ring system (r.m.s. deviation = 0.011 Å) forms a dihedral angle of 19.86 (6)° with the phenyl ring. The corresponding r.m.s. deviation and dihedral angle for the other mol­ecule are 0.014 Å and 22.32 (6)°, respectively. In the crystal, mol­ecules are linked via N—H⋯N, C—H⋯F and C—H⋯N hydrogen bonds into a three-dimensional network. The crystal studied was a non-merohedral twin with a refined BASF value of 0.301 (2).
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spelling pubmed-34143532012-08-17 1-(6-Fluoro-1,3-benzothia­zol-2-yl)-2-(1-phenyl­ethyl­idene)hydrazine Fun, Hoong-Kun Quah, Ching Kheng Munirajasekhar, D. Himaja, M. Sarojini, B. K. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(15)H(12)FN(3)S, consists of two independent mol­ecules with comparable geometries. In one mol­ecule, the 1,3-benzothia­zole ring system (r.m.s. deviation = 0.011 Å) forms a dihedral angle of 19.86 (6)° with the phenyl ring. The corresponding r.m.s. deviation and dihedral angle for the other mol­ecule are 0.014 Å and 22.32 (6)°, respectively. In the crystal, mol­ecules are linked via N—H⋯N, C—H⋯F and C—H⋯N hydrogen bonds into a three-dimensional network. The crystal studied was a non-merohedral twin with a refined BASF value of 0.301 (2). International Union of Crystallography 2012-07-14 /pmc/articles/PMC3414353/ /pubmed/22904886 http://dx.doi.org/10.1107/S1600536812030851 Text en © Fun et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Quah, Ching Kheng
Munirajasekhar, D.
Himaja, M.
Sarojini, B. K.
1-(6-Fluoro-1,3-benzothia­zol-2-yl)-2-(1-phenyl­ethyl­idene)hydrazine
title 1-(6-Fluoro-1,3-benzothia­zol-2-yl)-2-(1-phenyl­ethyl­idene)hydrazine
title_full 1-(6-Fluoro-1,3-benzothia­zol-2-yl)-2-(1-phenyl­ethyl­idene)hydrazine
title_fullStr 1-(6-Fluoro-1,3-benzothia­zol-2-yl)-2-(1-phenyl­ethyl­idene)hydrazine
title_full_unstemmed 1-(6-Fluoro-1,3-benzothia­zol-2-yl)-2-(1-phenyl­ethyl­idene)hydrazine
title_short 1-(6-Fluoro-1,3-benzothia­zol-2-yl)-2-(1-phenyl­ethyl­idene)hydrazine
title_sort 1-(6-fluoro-1,3-benzothia­zol-2-yl)-2-(1-phenyl­ethyl­idene)hydrazine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414353/
https://www.ncbi.nlm.nih.gov/pubmed/22904886
http://dx.doi.org/10.1107/S1600536812030851
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AT himajam 16fluoro13benzothiazol2yl21phenylethylidenehydrazine
AT sarojinibk 16fluoro13benzothiazol2yl21phenylethylidenehydrazine

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