A second monoclinic polymorph of N-[bis­(morpholin-4-yl)phosphino­yl]-4-fluoro­benzamide with the P2(1)/n space group

A second monoclinic polymorph of the title mol­ecule, C(15)H(21)FN(3)O(4)P, is reported in the space group P2(1)/n and compared to the previously reported C2/c space group [Gholivand et al. (2006 ▶). Polyhedron, 25, 711–721]. The asymmetric unit of the title compound consists of two independent mol­...

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Autores principales: Tarahhomi, Atekeh, Pourayoubi, Mehrdad, Keikha, Mojtaba, Rheingold, Arnold L., Golen, James A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414358/
https://www.ncbi.nlm.nih.gov/pubmed/22904891
http://dx.doi.org/10.1107/S1600536812031418
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author Tarahhomi, Atekeh
Pourayoubi, Mehrdad
Keikha, Mojtaba
Rheingold, Arnold L.
Golen, James A.
author_facet Tarahhomi, Atekeh
Pourayoubi, Mehrdad
Keikha, Mojtaba
Rheingold, Arnold L.
Golen, James A.
author_sort Tarahhomi, Atekeh
collection PubMed
description A second monoclinic polymorph of the title mol­ecule, C(15)H(21)FN(3)O(4)P, is reported in the space group P2(1)/n and compared to the previously reported C2/c space group [Gholivand et al. (2006 ▶). Polyhedron, 25, 711–721]. The asymmetric unit of the title compound consists of two independent mol­ecules. The P atoms adopt a distorted tetra­hedral environment. In the C(O)NHP(O) fragment, the P=O and the N—H groups are in a syn conformation with respect to each other and in the crystal, inter­molecular N—H⋯O=P hydrogen bonds form dimeric aggregates.
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spelling pubmed-34143582012-08-17 A second monoclinic polymorph of N-[bis­(morpholin-4-yl)phosphino­yl]-4-fluoro­benzamide with the P2(1)/n space group Tarahhomi, Atekeh Pourayoubi, Mehrdad Keikha, Mojtaba Rheingold, Arnold L. Golen, James A. Acta Crystallogr Sect E Struct Rep Online Organic Papers A second monoclinic polymorph of the title mol­ecule, C(15)H(21)FN(3)O(4)P, is reported in the space group P2(1)/n and compared to the previously reported C2/c space group [Gholivand et al. (2006 ▶). Polyhedron, 25, 711–721]. The asymmetric unit of the title compound consists of two independent mol­ecules. The P atoms adopt a distorted tetra­hedral environment. In the C(O)NHP(O) fragment, the P=O and the N—H groups are in a syn conformation with respect to each other and in the crystal, inter­molecular N—H⋯O=P hydrogen bonds form dimeric aggregates. International Union of Crystallography 2012-07-14 /pmc/articles/PMC3414358/ /pubmed/22904891 http://dx.doi.org/10.1107/S1600536812031418 Text en © Tarahhomi et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Tarahhomi, Atekeh
Pourayoubi, Mehrdad
Keikha, Mojtaba
Rheingold, Arnold L.
Golen, James A.
A second monoclinic polymorph of N-[bis­(morpholin-4-yl)phosphino­yl]-4-fluoro­benzamide with the P2(1)/n space group
title A second monoclinic polymorph of N-[bis­(morpholin-4-yl)phosphino­yl]-4-fluoro­benzamide with the P2(1)/n space group
title_full A second monoclinic polymorph of N-[bis­(morpholin-4-yl)phosphino­yl]-4-fluoro­benzamide with the P2(1)/n space group
title_fullStr A second monoclinic polymorph of N-[bis­(morpholin-4-yl)phosphino­yl]-4-fluoro­benzamide with the P2(1)/n space group
title_full_unstemmed A second monoclinic polymorph of N-[bis­(morpholin-4-yl)phosphino­yl]-4-fluoro­benzamide with the P2(1)/n space group
title_short A second monoclinic polymorph of N-[bis­(morpholin-4-yl)phosphino­yl]-4-fluoro­benzamide with the P2(1)/n space group
title_sort second monoclinic polymorph of n-[bis­(morpholin-4-yl)phosphino­yl]-4-fluoro­benzamide with the p2(1)/n space group
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414358/
https://www.ncbi.nlm.nih.gov/pubmed/22904891
http://dx.doi.org/10.1107/S1600536812031418
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