2-[(4-Meth­oxy-2-nitro­phen­yl)imino­meth­yl]phenol

The crystal structure of the title compound, C(14)H(12)N(2)O(4), contains four crystallographically independent mol­ecules in the asymmetric unit. All the mol­ecules have similar conformations; the dihedral angles between the aromatic rings are 33.1 (1), 33.76 (9), 31.41 (9) and 32.56 (10)°. Intra­m...

Descripción completa

Detalles Bibliográficos
Autores principales: Khalaji, Aliakbar Dehno, Nikookar, Mahsa, Fejfarová, Karla, Dušek, Michal
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414359/
https://www.ncbi.nlm.nih.gov/pubmed/22904892
http://dx.doi.org/10.1107/S1600536812031212
_version_ 1782240201096036352
author Khalaji, Aliakbar Dehno
Nikookar, Mahsa
Fejfarová, Karla
Dušek, Michal
author_facet Khalaji, Aliakbar Dehno
Nikookar, Mahsa
Fejfarová, Karla
Dušek, Michal
author_sort Khalaji, Aliakbar Dehno
collection PubMed
description The crystal structure of the title compound, C(14)H(12)N(2)O(4), contains four crystallographically independent mol­ecules in the asymmetric unit. All the mol­ecules have similar conformations; the dihedral angles between the aromatic rings are 33.1 (1), 33.76 (9), 31.41 (9) and 32.56 (10)°. Intra­molecular O—H⋯N hydrogen bonds form S(6) ring motifs in each molecule. In the crystal, there are two pairs of pseudo-inversion-related mol­ecules. Along the c axis, mol­ecules are stacked with π–π inter­actions between the 2-hy­droxy­phenyl and 4-meth­oxy-2-nitro­phenyl rings [centroid–centroid distances = 3.5441 (12)–3.7698 (12) Å].
format Online
Article
Text
id pubmed-3414359
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-34143592012-08-17 2-[(4-Meth­oxy-2-nitro­phen­yl)imino­meth­yl]phenol Khalaji, Aliakbar Dehno Nikookar, Mahsa Fejfarová, Karla Dušek, Michal Acta Crystallogr Sect E Struct Rep Online Organic Papers The crystal structure of the title compound, C(14)H(12)N(2)O(4), contains four crystallographically independent mol­ecules in the asymmetric unit. All the mol­ecules have similar conformations; the dihedral angles between the aromatic rings are 33.1 (1), 33.76 (9), 31.41 (9) and 32.56 (10)°. Intra­molecular O—H⋯N hydrogen bonds form S(6) ring motifs in each molecule. In the crystal, there are two pairs of pseudo-inversion-related mol­ecules. Along the c axis, mol­ecules are stacked with π–π inter­actions between the 2-hy­droxy­phenyl and 4-meth­oxy-2-nitro­phenyl rings [centroid–centroid distances = 3.5441 (12)–3.7698 (12) Å]. International Union of Crystallography 2012-07-14 /pmc/articles/PMC3414359/ /pubmed/22904892 http://dx.doi.org/10.1107/S1600536812031212 Text en © Khalaji et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Khalaji, Aliakbar Dehno
Nikookar, Mahsa
Fejfarová, Karla
Dušek, Michal
2-[(4-Meth­oxy-2-nitro­phen­yl)imino­meth­yl]phenol
title 2-[(4-Meth­oxy-2-nitro­phen­yl)imino­meth­yl]phenol
title_full 2-[(4-Meth­oxy-2-nitro­phen­yl)imino­meth­yl]phenol
title_fullStr 2-[(4-Meth­oxy-2-nitro­phen­yl)imino­meth­yl]phenol
title_full_unstemmed 2-[(4-Meth­oxy-2-nitro­phen­yl)imino­meth­yl]phenol
title_short 2-[(4-Meth­oxy-2-nitro­phen­yl)imino­meth­yl]phenol
title_sort 2-[(4-meth­oxy-2-nitro­phen­yl)imino­meth­yl]phenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414359/
https://www.ncbi.nlm.nih.gov/pubmed/22904892
http://dx.doi.org/10.1107/S1600536812031212
work_keys_str_mv AT khalajialiakbardehno 24methoxy2nitrophenyliminomethylphenol
AT nikookarmahsa 24methoxy2nitrophenyliminomethylphenol
AT fejfarovakarla 24methoxy2nitrophenyliminomethylphenol
AT dusekmichal 24methoxy2nitrophenyliminomethylphenol

Ejemplares similares