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6-Aminonicotinamide
In the title compound, C(6)H(7)N(3)O, the amide group is rotated such that the carbonyl O atom is syn to the pyridine N atom, with an O—C—C—C torsion angle of −23.55 (18)°. The crystal packing involves four hydrogen bonds of the types N—H⋯N and N—H⋯O. Two separate centrosymmetric rings are formed us...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414361/ https://www.ncbi.nlm.nih.gov/pubmed/22904894 http://dx.doi.org/10.1107/S1600536812031224 |
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author | Ntsala, Lerato P. Lemmerer, Andreas |
author_facet | Ntsala, Lerato P. Lemmerer, Andreas |
author_sort | Ntsala, Lerato P. |
collection | PubMed |
description | In the title compound, C(6)H(7)N(3)O, the amide group is rotated such that the carbonyl O atom is syn to the pyridine N atom, with an O—C—C—C torsion angle of −23.55 (18)°. The crystal packing involves four hydrogen bonds of the types N—H⋯N and N—H⋯O. Two separate centrosymmetric rings are formed using N—H⋯N and N—H⋯O hydrogen bonds that result in a ribbon of 6-aminonicotinamide molecules, joined by the amide and amine functional groups. The remaining two hydrogen bonds are used to generate a three-dimensional packing arrangement. |
format | Online Article Text |
id | pubmed-3414361 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-34143612012-08-17 6-Aminonicotinamide Ntsala, Lerato P. Lemmerer, Andreas Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(6)H(7)N(3)O, the amide group is rotated such that the carbonyl O atom is syn to the pyridine N atom, with an O—C—C—C torsion angle of −23.55 (18)°. The crystal packing involves four hydrogen bonds of the types N—H⋯N and N—H⋯O. Two separate centrosymmetric rings are formed using N—H⋯N and N—H⋯O hydrogen bonds that result in a ribbon of 6-aminonicotinamide molecules, joined by the amide and amine functional groups. The remaining two hydrogen bonds are used to generate a three-dimensional packing arrangement. International Union of Crystallography 2012-07-14 /pmc/articles/PMC3414361/ /pubmed/22904894 http://dx.doi.org/10.1107/S1600536812031224 Text en © Ntsala and Lemmerer 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Ntsala, Lerato P. Lemmerer, Andreas 6-Aminonicotinamide |
title | 6-Aminonicotinamide |
title_full | 6-Aminonicotinamide |
title_fullStr | 6-Aminonicotinamide |
title_full_unstemmed | 6-Aminonicotinamide |
title_short | 6-Aminonicotinamide |
title_sort | 6-aminonicotinamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414361/ https://www.ncbi.nlm.nih.gov/pubmed/22904894 http://dx.doi.org/10.1107/S1600536812031224 |
work_keys_str_mv | AT ntsalaleratop 6aminonicotinamide AT lemmererandreas 6aminonicotinamide |