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6-Amino­nicotinamide

In the title compound, C(6)H(7)N(3)O, the amide group is rotated such that the carbonyl O atom is syn to the pyridine N atom, with an O—C—C—C torsion angle of −23.55 (18)°. The crystal packing involves four hydrogen bonds of the types N—H⋯N and N—H⋯O. Two separate centrosymmetric rings are formed us...

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Detalles Bibliográficos
Autores principales: Ntsala, Lerato P., Lemmerer, Andreas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414361/
https://www.ncbi.nlm.nih.gov/pubmed/22904894
http://dx.doi.org/10.1107/S1600536812031224
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author Ntsala, Lerato P.
Lemmerer, Andreas
author_facet Ntsala, Lerato P.
Lemmerer, Andreas
author_sort Ntsala, Lerato P.
collection PubMed
description In the title compound, C(6)H(7)N(3)O, the amide group is rotated such that the carbonyl O atom is syn to the pyridine N atom, with an O—C—C—C torsion angle of −23.55 (18)°. The crystal packing involves four hydrogen bonds of the types N—H⋯N and N—H⋯O. Two separate centrosymmetric rings are formed using N—H⋯N and N—H⋯O hydrogen bonds that result in a ribbon of 6-aminonicotinamide molecules, joined by the amide and amine functional groups. The remaining two hydrogen bonds are used to generate a three-dimensional packing arrangement.
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spelling pubmed-34143612012-08-17 6-Amino­nicotinamide Ntsala, Lerato P. Lemmerer, Andreas Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(6)H(7)N(3)O, the amide group is rotated such that the carbonyl O atom is syn to the pyridine N atom, with an O—C—C—C torsion angle of −23.55 (18)°. The crystal packing involves four hydrogen bonds of the types N—H⋯N and N—H⋯O. Two separate centrosymmetric rings are formed using N—H⋯N and N—H⋯O hydrogen bonds that result in a ribbon of 6-aminonicotinamide molecules, joined by the amide and amine functional groups. The remaining two hydrogen bonds are used to generate a three-dimensional packing arrangement. International Union of Crystallography 2012-07-14 /pmc/articles/PMC3414361/ /pubmed/22904894 http://dx.doi.org/10.1107/S1600536812031224 Text en © Ntsala and Lemmerer 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ntsala, Lerato P.
Lemmerer, Andreas
6-Amino­nicotinamide
title 6-Amino­nicotinamide
title_full 6-Amino­nicotinamide
title_fullStr 6-Amino­nicotinamide
title_full_unstemmed 6-Amino­nicotinamide
title_short 6-Amino­nicotinamide
title_sort 6-amino­nicotinamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414361/
https://www.ncbi.nlm.nih.gov/pubmed/22904894
http://dx.doi.org/10.1107/S1600536812031224
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