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N-Butyl-4-butyl­imino-2-methyl­pentan-2-aminium (E)-quercetinate

The title salt, C(14)H(31)N(2) (+)·C(15)H(9)O(7) (−), was obtained in the reaction of quercetin with n-butyl­amine in a mixture of acetone and hexane. The crystal structure determination shows that the quercetin donates one of its phenol H atoms to the N-butyl-4-butyl­imino-2-methyl­pentan-2-amine m...

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Detalles Bibliográficos
Autores principales: Grosu, Ioana-Georgeta, Borodi, Gheorghe, Pop, Mihaela Maria
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414362/
https://www.ncbi.nlm.nih.gov/pubmed/22904895
http://dx.doi.org/10.1107/S1600536812031170
Descripción
Sumario:The title salt, C(14)H(31)N(2) (+)·C(15)H(9)O(7) (−), was obtained in the reaction of quercetin with n-butyl­amine in a mixture of acetone and hexane. The crystal structure determination shows that the quercetin donates one of its phenol H atoms to the N-butyl-4-butyl­imino-2-methyl­pentan-2-amine mol­ecule. The crystal structure of the salt is stabilized by intramolecular (N—H⋯N for the cation and O—H⋯O for the anion) and intermolecular hydrogen bonding (N—H⋯O between cation–anion pairs and O—H⋯O between anions). Quercetin molecules form dimers connected into a two-dimensional network. The dihedral angle between the quercetin ring systems is 19.61 (8)°.