(R)-2-Methyl-5-[(R)-2,4,4,4-tetra­chloro­butan-2-yl]cyclo­hex-2-enone

The title compound, C(11)H(14)Cl(4)O, was efficiently synthesized by atom-transfer radical addition between (R)-carvone and tetra­chloro­methane. In the mol­ecule, both chiral centres are of the absolute configuration R. The cyclo­hex-2-enone ring has an envelope conformation with the chiral C atom...

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Detalles Bibliográficos
Autores principales: Boualy, Brahim, Harrad, Mohamed Anouar, El Firdoussi, Larbi, Ali, Mustapha Ait, Stoeckli-Evans, Helen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414363/
https://www.ncbi.nlm.nih.gov/pubmed/22904896
http://dx.doi.org/10.1107/S1600536812031194
Descripción
Sumario:The title compound, C(11)H(14)Cl(4)O, was efficiently synthesized by atom-transfer radical addition between (R)-carvone and tetra­chloro­methane. In the mol­ecule, both chiral centres are of the absolute configuration R. The cyclo­hex-2-enone ring has an envelope conformation with the chiral C atom displaced by 0.633 (2) Å from the mean plane through the other five C atoms [maximum deviation = 0.036 (2) Å]. In the crystal, mol­ecules are linked via C—H⋯O inter­actions, leading to the formation of helical chains propagating along [100].

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