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1-(2,4-Difluorophenyl)thiourea
The asymmetric unit of the title compound, C(7)H(6)F(2)N(2)S, consists of two independent molecules, with comparable geometries. In one molecule, the thiourea moiety is essentially planar (r.m.s. deviation = 0.014 Å) and it forms a dihedral angle of 78.67 (9)° with the benzene ring. The correspon...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414916/ https://www.ncbi.nlm.nih.gov/pubmed/22904903 http://dx.doi.org/10.1107/S1600536812031625 |
Sumario: | The asymmetric unit of the title compound, C(7)H(6)F(2)N(2)S, consists of two independent molecules, with comparable geometries. In one molecule, the thiourea moiety is essentially planar (r.m.s. deviation = 0.014 Å) and it forms a dihedral angle of 78.67 (9)° with the benzene ring. The corresponding r.m.s. deviation and dihedral angle for the other molecule are 0.011 Å and 81.71 (8)°, respectively. In both molecules, one of the F atoms is disordered over two positions with refined site occupancies of 0.572 (3):0.428 (3) and 0.909 (2):0.091 (2), respectively. In the crystal, molecules are linked via N—H⋯S and C—H⋯F hydrogen bonds into two-dimensional networks parallel to (010). |
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