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5-Fluoro-3-(3-fluorophenylsulfonyl)-2-methyl-1-benzofuran
In the title compound, C(15)H(10)F(2)O(3)S, the 3-fluorophenyl ring makes a dihedral angle of 79.51 (6)° with the mean plane [r.m.s. deviation = 0.006 (2) Å] of the benzofuran fragment. In the crystal, molecules are linked by weak C—H⋯F and C—H⋯O hydrogen bonds. The crystal structure also exhibits...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414932/ https://www.ncbi.nlm.nih.gov/pubmed/22904919 http://dx.doi.org/10.1107/S1600536812031972 |
Sumario: | In the title compound, C(15)H(10)F(2)O(3)S, the 3-fluorophenyl ring makes a dihedral angle of 79.51 (6)° with the mean plane [r.m.s. deviation = 0.006 (2) Å] of the benzofuran fragment. In the crystal, molecules are linked by weak C—H⋯F and C—H⋯O hydrogen bonds. The crystal structure also exhibits slipped π–π interactions between the benzene and furan rings of neighbouring molecules [centroid–centroid distances = 3.563 (3) and 3.820 (3) Å and slippages of 0.358 (3)and 1.551 (3) Å]. In the 3-fluorophenyl ring, the F atom is disordered over two positions with site-occupancy factors of 0.887 (3) and 0.113 (3). |
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