3-Bromo-2-hy­droxy­benzaldehyde

The mol­ecule of the title compound, C(7)H(5)BrO(2), is almost planar (r.m.s. deviation from the plane of all the non-H atoms = 0.0271 Å) and displays intra­molecular O—H⋯O hydrogen bonding between the phenol group and the aldehyde O atom. Packing is directed by weak inter­molecular C—H⋯Br inter­act...

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Detalles Bibliográficos
Autores principales: Metlay, Jessica B., Tanski, Joseph M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414939/
https://www.ncbi.nlm.nih.gov/pubmed/22904926
http://dx.doi.org/10.1107/S1600536812031510
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author Metlay, Jessica B.
Tanski, Joseph M.
author_facet Metlay, Jessica B.
Tanski, Joseph M.
author_sort Metlay, Jessica B.
collection PubMed
description The mol­ecule of the title compound, C(7)H(5)BrO(2), is almost planar (r.m.s. deviation from the plane of all the non-H atoms = 0.0271 Å) and displays intra­molecular O—H⋯O hydrogen bonding between the phenol group and the aldehyde O atom. Packing is directed by weak inter­molecular C—H⋯Br inter­actions and π-stacking between nearly parallel mol­ecules [dihedral angle = 5.30 (6)° and centroid–centroid distance = 3.752 (1) Å].
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spelling pubmed-34149392012-08-17 3-Bromo-2-hy­droxy­benzaldehyde Metlay, Jessica B. Tanski, Joseph M. Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title compound, C(7)H(5)BrO(2), is almost planar (r.m.s. deviation from the plane of all the non-H atoms = 0.0271 Å) and displays intra­molecular O—H⋯O hydrogen bonding between the phenol group and the aldehyde O atom. Packing is directed by weak inter­molecular C—H⋯Br inter­actions and π-stacking between nearly parallel mol­ecules [dihedral angle = 5.30 (6)° and centroid–centroid distance = 3.752 (1) Å]. International Union of Crystallography 2012-07-18 /pmc/articles/PMC3414939/ /pubmed/22904926 http://dx.doi.org/10.1107/S1600536812031510 Text en © Metlay and Tanski 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Metlay, Jessica B.
Tanski, Joseph M.
3-Bromo-2-hy­droxy­benzaldehyde
title 3-Bromo-2-hy­droxy­benzaldehyde
title_full 3-Bromo-2-hy­droxy­benzaldehyde
title_fullStr 3-Bromo-2-hy­droxy­benzaldehyde
title_full_unstemmed 3-Bromo-2-hy­droxy­benzaldehyde
title_short 3-Bromo-2-hy­droxy­benzaldehyde
title_sort 3-bromo-2-hy­droxy­benzaldehyde
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414939/
https://www.ncbi.nlm.nih.gov/pubmed/22904926
http://dx.doi.org/10.1107/S1600536812031510
work_keys_str_mv AT metlayjessicab 3bromo2hydroxybenzaldehyde
AT tanskijosephm 3bromo2hydroxybenzaldehyde

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