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N-[4-(4-Nitrophenoxy)phenyl]acetamide
The asymmetric unit of the title compound, C(14)H(12)N(2)O(4), contains two molecules that differ principally in the orientation of the acetamide substituent to the adjacent benzene ring with dihedral angles of 44.77 (7) and 19.06 (7)°. The dihedral angles between the benzene rings are 64.46 (4) an...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414940/ https://www.ncbi.nlm.nih.gov/pubmed/22904927 http://dx.doi.org/10.1107/S1600536812031856 |
Sumario: | The asymmetric unit of the title compound, C(14)H(12)N(2)O(4), contains two molecules that differ principally in the orientation of the acetamide substituent to the adjacent benzene ring with dihedral angles of 44.77 (7) and 19.06 (7)°. The dihedral angles between the benzene rings are 64.46 (4) and 80.84 (4)°. In the crystal, classical N—H⋯O hydrogen bonds form C(4) chains along [100]. These chains are interlinked by C—H⋯O contacts forming R (2) (2)(10) rings. In the crystal, π–π interactions are observed with a distance of 3.5976 (18) Å between the centroids of the nitro-substituted benzene rings of one type of molecule. |
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