N-[4-(4-Nitro­phen­oxy)phen­yl]acetamide

The asymmetric unit of the title compound, C(14)H(12)N(2)O(4), contains two mol­ecules that differ principally in the orientation of the acetamide substituent to the adjacent benzene ring with dihedral angles of 44.77 (7) and 19.06 (7)°. The dihedral angles between the benzene rings are 64.46 (4) an...

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Detalles Bibliográficos
Autores principales: Nigar, Asifa, Akhter, Zareen, Tahir, M. Nawaz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414940/
https://www.ncbi.nlm.nih.gov/pubmed/22904927
http://dx.doi.org/10.1107/S1600536812031856
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author Nigar, Asifa
Akhter, Zareen
Tahir, M. Nawaz
author_facet Nigar, Asifa
Akhter, Zareen
Tahir, M. Nawaz
author_sort Nigar, Asifa
collection PubMed
description The asymmetric unit of the title compound, C(14)H(12)N(2)O(4), contains two mol­ecules that differ principally in the orientation of the acetamide substituent to the adjacent benzene ring with dihedral angles of 44.77 (7) and 19.06 (7)°. The dihedral angles between the benzene rings are 64.46 (4) and 80.84 (4)°. In the crystal, classical N—H⋯O hydrogen bonds form C(4) chains along [100]. These chains are inter­linked by C—H⋯O contacts forming R (2) (2)(10) rings. In the crystal, π–π inter­actions are observed with a distance of 3.5976 (18) Å between the centroids of the nitro-substituted benzene rings of one type of mol­ecule.
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spelling pubmed-34149402012-08-17 N-[4-(4-Nitro­phen­oxy)phen­yl]acetamide Nigar, Asifa Akhter, Zareen Tahir, M. Nawaz Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(14)H(12)N(2)O(4), contains two mol­ecules that differ principally in the orientation of the acetamide substituent to the adjacent benzene ring with dihedral angles of 44.77 (7) and 19.06 (7)°. The dihedral angles between the benzene rings are 64.46 (4) and 80.84 (4)°. In the crystal, classical N—H⋯O hydrogen bonds form C(4) chains along [100]. These chains are inter­linked by C—H⋯O contacts forming R (2) (2)(10) rings. In the crystal, π–π inter­actions are observed with a distance of 3.5976 (18) Å between the centroids of the nitro-substituted benzene rings of one type of mol­ecule. International Union of Crystallography 2012-07-18 /pmc/articles/PMC3414940/ /pubmed/22904927 http://dx.doi.org/10.1107/S1600536812031856 Text en © Nigar et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Nigar, Asifa
Akhter, Zareen
Tahir, M. Nawaz
N-[4-(4-Nitro­phen­oxy)phen­yl]acetamide
title N-[4-(4-Nitro­phen­oxy)phen­yl]acetamide
title_full N-[4-(4-Nitro­phen­oxy)phen­yl]acetamide
title_fullStr N-[4-(4-Nitro­phen­oxy)phen­yl]acetamide
title_full_unstemmed N-[4-(4-Nitro­phen­oxy)phen­yl]acetamide
title_short N-[4-(4-Nitro­phen­oxy)phen­yl]acetamide
title_sort n-[4-(4-nitro­phen­oxy)phen­yl]acetamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414940/
https://www.ncbi.nlm.nih.gov/pubmed/22904927
http://dx.doi.org/10.1107/S1600536812031856
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AT akhterzareen n44nitrophenoxyphenylacetamide
AT tahirmnawaz n44nitrophenoxyphenylacetamide

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