4-[(4-Chloro­phen­yl)(phen­yl)­meth­yl]­piperazin-1-ium picrate monohydrate

The asymmetric unit of the title compound, C(17)H(20)ClN(2) (+)·C(6)H(2)N(3)O(7) (−)·H(2)O, contains a piperazin-1-ium cation, a picrate anion and one solvent water mol­ecule. The piperazene ring is protonated at one N atom and adopts a highly distorted chair conformation with the chloro­pheny(phen­...

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Detalles Bibliográficos
Autores principales: Song, Yanxi, Chidan Kumar, C. S., Chandraju, S., Naveen, S., Li, Hongqi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414941/
https://www.ncbi.nlm.nih.gov/pubmed/22904928
http://dx.doi.org/10.1107/S1600536812031984
Descripción
Sumario:The asymmetric unit of the title compound, C(17)H(20)ClN(2) (+)·C(6)H(2)N(3)O(7) (−)·H(2)O, contains a piperazin-1-ium cation, a picrate anion and one solvent water mol­ecule. The piperazene ring is protonated at one N atom and adopts a highly distorted chair conformation with the chloro­pheny(phen­yl)methyl substituent on the second N atom in an equatorial position. The crystal structure is stabilized by O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds.

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