Pseudoaglycone of Spinosyn A

The title compound [systematic name: 9-ethyl-13-hy­droxy-14-methyl-2-(3,4,5-trimeth­oxy-6-methyl­tetra­hydro-2H-pyran-2-yl­oxy)-3,3a,5b,6,9,10,11,12,13,14,16a,16b-dodeca­hydro-1H-as-indaceno[3,2-d][1]oxacyclo­dodecine-7,15(2H,5aH)-dione], C(33)H(50)O(9), was obtained by hydrolysis of Spinosyn A. The...

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Detalles Bibliográficos
Autores principales: Chai, Hongxin, Liu, Mingxing, Zhang, Qi, Shi, Daxin, Li, Jiarong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414943/
https://www.ncbi.nlm.nih.gov/pubmed/22904930
http://dx.doi.org/10.1107/S1600536812028851
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author Chai, Hongxin
Liu, Mingxing
Zhang, Qi
Shi, Daxin
Li, Jiarong
author_facet Chai, Hongxin
Liu, Mingxing
Zhang, Qi
Shi, Daxin
Li, Jiarong
author_sort Chai, Hongxin
collection PubMed
description The title compound [systematic name: 9-ethyl-13-hy­droxy-14-methyl-2-(3,4,5-trimeth­oxy-6-methyl­tetra­hydro-2H-pyran-2-yl­oxy)-3,3a,5b,6,9,10,11,12,13,14,16a,16b-dodeca­hydro-1H-as-indaceno[3,2-d][1]oxacyclo­dodecine-7,15(2H,5aH)-dione], C(33)H(50)O(9), was obtained by hydrolysis of Spinosyn A. The fused cyclo­pentene ring adopts a twisted conformation, while the fused cyclo­hexene and cyclo­pentane rings are in envelope conformations with the same C atom at the flaps. In the crystal, mol­ecules are linked by O—H⋯O and C—H⋯O hydrogen bonds into a layer parallel to the ab plane.
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spelling pubmed-34149432012-08-17 Pseudoaglycone of Spinosyn A Chai, Hongxin Liu, Mingxing Zhang, Qi Shi, Daxin Li, Jiarong Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound [systematic name: 9-ethyl-13-hy­droxy-14-methyl-2-(3,4,5-trimeth­oxy-6-methyl­tetra­hydro-2H-pyran-2-yl­oxy)-3,3a,5b,6,9,10,11,12,13,14,16a,16b-dodeca­hydro-1H-as-indaceno[3,2-d][1]oxacyclo­dodecine-7,15(2H,5aH)-dione], C(33)H(50)O(9), was obtained by hydrolysis of Spinosyn A. The fused cyclo­pentene ring adopts a twisted conformation, while the fused cyclo­hexene and cyclo­pentane rings are in envelope conformations with the same C atom at the flaps. In the crystal, mol­ecules are linked by O—H⋯O and C—H⋯O hydrogen bonds into a layer parallel to the ab plane. International Union of Crystallography 2012-07-18 /pmc/articles/PMC3414943/ /pubmed/22904930 http://dx.doi.org/10.1107/S1600536812028851 Text en © Chai et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Chai, Hongxin
Liu, Mingxing
Zhang, Qi
Shi, Daxin
Li, Jiarong
Pseudoaglycone of Spinosyn A
title Pseudoaglycone of Spinosyn A
title_full Pseudoaglycone of Spinosyn A
title_fullStr Pseudoaglycone of Spinosyn A
title_full_unstemmed Pseudoaglycone of Spinosyn A
title_short Pseudoaglycone of Spinosyn A
title_sort pseudoaglycone of spinosyn a
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414943/
https://www.ncbi.nlm.nih.gov/pubmed/22904930
http://dx.doi.org/10.1107/S1600536812028851
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AT liumingxing pseudoaglyconeofspinosyna
AT zhangqi pseudoaglyconeofspinosyna
AT shidaxin pseudoaglyconeofspinosyna
AT lijiarong pseudoaglyconeofspinosyna

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